Chemistry Reference
In-Depth Information
The equation is:
heat
a.
b.
3.26
O
CN
c.
NO
2
3.27
3.28
3.29
a.
b.
c.
d.
3.30
Follow eq. 3.53 as a guideline:
C
-
Na
+
C H
(C H)
3
C
C
H
+
NaNH
2
C H
(C H)
3
C
+NH
3.31
C
-
Na
+
H
C
+
H
H
C
C
H
+
NaOH
3.32
2-Hexyne has no hydrogens on the triple bond:
Therefore, it does not react with sodium amide.
ADDITIONAL PROBLEMS
3.33
In each case, start with the longest possible chain and determine all possible
positions for the double bond. Then shorten the chain by one carbon and repeat, and
so on.
