Chemistry Reference
In-Depth Information
Empirical formula: C
14
H
18
N
2
O
3
MnCl
2
Shannon entropy of atomic numbers: 1.3128
Shannon entropy of bond orders: 0.8766
4.4.16 e
xaMple
16
The bimetallic complex in Figure 4.24 was obtained recently by a synthesis involving
a small number of steps (Mendoza-Espinosa et al. 2011). The charge on the analyzed
system is +1.
The value of bond order for Pd-Cl: 0.789
The value of bond order for Pd-C: 0.802
Sum of bond orders for Pd (all types of bonds): 1.898
Free valence for Pd: +4.102
X
X
Y
Cl
P
Au
N
Pd
Cl
N
Y
X = Ph
Y = 2,6-diisopropylphenyl
FIGURE 4.24A
The 2D structure of bimetallic complex in example 16.
FIGURE 4.24B
The 3D structure of bimetallic complex in example 16 without hydrogen
atoms.
