Biomedical Engineering Reference
In-Depth Information
Table 9.16
Phase behavior of lanthanide complexes
69-71
.
Compound
R
1
R
2
M
Phase transition behavior
69a
X
H
Er
g 150 Col
h
180 Cub 185 I
69b
X
H
Tm
g 160 Col
L
180 I
69c
X
H
Yb
g 175 Col
h
195 I
69d
X
H
Lu
g 155 Col
h
190 I
70a
H
X
Er
g 160 Col
h
221 dec
70b
H
X
Tm
g 160 Col
h
221 dec
70c
H
X
Yb
g 160 Col
h
223 dec
70d
H
X
Lu
g 160 Col
h
223 dec
71
H
Y
Lu
g 170 Col
h
250 dec
OR
OR
OR
OR
OR
OR
RO
RO
O
O
O
O
O
O
M
M
O
O
O
O
O
O
RO
OR
RO
OR
X
X
OR
OR
OR
OR
74a-g
73a-g
Figure 9.28
Ionic discotic compounds of Crown ethers with terphenyl
73a-g
and with
triphenylene
74a-g.
Table 9.17
Phase behavior of [18]-crown 6 complexes of terphenyl
and triphenylen
e.
Compound
R
X
Phase transition behavior
73
a
C
11
H
23
F
Cr 65 Col
h
80 I
73b
C
11
H
23
Cl
Cr 75 Col
h
81 I
73c
C
11
H
23
Br
Cr 79 Col
h
99 I
73d
C
11
H
23
I
Cr 90 Col
h
145 I
(
Continued
)
