Environmental Engineering Reference
In-Depth Information
Mass balances in the products compared to dried substrate
100%
1.71%
16.73%
90%
18.10%
80%
18.58%
70%
60%
gas + total loss
50%
100.00%
liquid
40%
80.19%
64.69%
30%
solid
20%
10%
0%
Substrate
Paper-Coal (200 ° C
Paper-Coal (220 ° C)
Substrates
Figure 6.9. Results of mass balances, substrate and products (Krüger, 2011).
Figure 6.10. Results of three heating value analysis, substrate and products (Krüger, 2011).
With respect to technological implementation of HTC, also the by-products have a strongmatter
of interest.
An important by-product from the HTC process is the process water. Several utilizations are
imaginable, such as biogas production in high load fixed bed digesters or separation into individu-
ally utilizable fractions via continuous distillation (so-called fractioned rectification). Concerning
development of such utilization strategies knowledge about the process water composition is abso-
lutely required. Figure 6.14 shows quantitativeGCMS analysis results of process waters fromHTC
batch processes being operated for 1, 3, 6 and 21 hours with the same substrate. The values were
standardized to the highest value being measured for each single compound.
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