Chemistry Reference
In-Depth Information
Earlier, however, it was speculated that guanidyl urea forms [ 140 ].
The curing mechanism of epoxy resins with imidazole was investigated. The following mecha-
nism was proposed [ 137 ]:
O
O
NN
H
+
H
NN
H
NN
C 2 H 5
C 2 H 5
C 2 H 5
O
OH
H
NN
NN
C 2 H 5
C 2 H 5
OH
or
NN
O
C 2 H 5
O
OH
NN
C 2 H 5
Many cyclic acid anhydrides are used industrially for cross-linking epoxy resins. These are mono
and polyanhydrides. Following are some typical commercially used anhydrides:
O
O
O
O
O
O
O
O
O
O
O
O
pyromellitic
dianhydride
phthalic
anhydride
maleic
anhydride
Cl
O
O
Cl
O
O
Cl
Cl
O
O
C 12 H 23
O
CH 3
O
dodecylsuccinic
anhydride
O
Cl
methylbicyclo [2,2,1]hept-5-
ene-2,3-dicarboxylic acid
anhydride
Cl
chlorendic
anhydride
O
O
O
O
R
O
O
photoadduct of alkylbenzene
and maleic anhydride 138
 
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