Chemistry Reference
In-Depth Information
3. Describe the termination reaction in cyclic sulfides cationic polymerizations.
4. What type of side reactions can occur in anionic polymerizations of cyclic sulfides?
Section 5.14
1. Discuss copolymerizations of cyclic monomers giving several examples.
Section 5.15
1. How does a spontaneous zwitterion copolymerization occur. Explain.
2. What is meant by a genetic zwitterion?
3. Give several examples of zwitterion copolymerization.
Section 5.16
1. Explain ring-opening polymerizations by free-radical mechanism, giving two examples.
Recommended Reading
K.J. Ivin and J.C. Mol,
Olefin Metathesis and Metathesis Polymerization
, Academic Press, San Diego, 1997
References
1. M. Hitota and H. Fukuda, Makromol. Chem.,
188
, 2259 (1987); see also:F. Afsahar-Taroni, M. Scheer, P. Rempp,
and E. Fanata, Makromol. Chem.,
1978
,
179
, 849
2. J. Furukawa and T. Saegusa,
Polymerization of Aldehydes and Oxides
, Interscience, Wiley, New York,
1963
;S.
Penczek and P. Kubisa, “Cationic Ring Opening Polymerization: Ethers” Chapt. 48 in “Comprehensive Polymer
Science”, Vol. 3, (G.C. Eastmond, A. Ledwith, S. Russo, and P. Sigwalt, eds.), Pergamon Press, London,
1989
3. R.D. Colclough, G. Gee, W.C.E. Higginson, J.B. Jackson, and M. Litt,
J. Polymer Sci.
,
1959 34
, 171
4. A.M. Eastham,
Fortschr. Hochpolymer.-Forsch.
,
1961
,
2
,18
5. D.J. Worsford and A. M Eastham,
J. Am. Chem. Soc.
,
1957
,
79
, 897
6. G.T. Merall, G.A. Latremouille, and A.M. Eastham,
J. Am. Chem. Soc.
,
1960
,
82
, 120
7. S. Searles and M. Tamres,
J. Am. Chem. Soc.
,
1951
,
73
, 3704
8. E. J. Vandenberg,
J. Am. Chem. Soc.,1961
,
83
, 3538 ;
J. Polymer Sci
,
1964, B,2,
1085 ;
J. Polymer Sci.
,
1969 A- 1,
7
, 525
9. C.C. Price and R. Spector,
, 4171
10. T.L. Cairns and R.M. Joyce, Jr., U.S. Patent #2,445,912 (
1948
)
11. E.J. Vandenberg,
JAm
.
Chem
.
Soc
.
,
1966
,
88
, 489
12. B. Aydogan, G. E. Gunbas, A. Durmus, L. Toppare. and Y. Yagci,
J. Polymer Sci
.
,
1960
,
47
Macromolecules
,
2010
, 43, 101
13. E. Roithner,
Monatsch
.
Chem
.
,
15
, 679 (
1894);
J. Chem
.
Soc
.
,
68
(1), 319 (
1895
)
14. S. Perry and H. Hibbert,
J. Am
.
Chem
.
Soc
.
,
62
, 2599 (1940); S. Perry and H. Hibbert,
Can
.
J. Res
.
,
1953
,
8
, 102
15. J. Raynaud, Y. Gnanou, and D. Taton,
Am. Chem. Soc. Polymer Preprints
, 2009
,
50
(2), 216
