Chemistry Reference
In-Depth Information
3. What is the mechanism control in anionic polymerization of aldehydes polymerizations?
4. Describe polymerization of unsaturated aldehydes such as crotonaldehyde or acrolein.
5. Describe polymerization of dialdehydes.
Section 4.7
1. Discuss polymerization of ketones and isocyanates.
Section 4.8
1. Discuss copolymerization by ionic mechanism. What am some of the problems that are
encountered?
Section 4.9
1. Discuss the proposed mechanisms of group transfer polymerization.
Section 4.10
1. What are Bernoulli, Markov, and Colman-Fox statistical models for the propagation reactions?
Can you describe each?
Recommended Reading
H.L. Hsieh and R.P. Quick,
Anionic Polymerization - Principles and Practical Applications
, M. Dekker, New York,
1996
K. Matyjaszewski, ed.,
Cationic Polymerization - Mechanism, Synthesis and Application,
M. Dekker, New York, 1996
References
1. J.P. Kennedy and E. Marechal,
Cationic Polymerization
, Wiley-Interscience, New York 1982; M.Mofton,
Anionic
Polymerization, Principles and Practice
, Academic Press New York 1983
2. T.E. HogenEsch and J. Smid, eds,
Recent Advances in Anionic Polymerization
, Elsevier, New York, 1987
3. M.L Burstall and FE. Treloar, Chapt. 1,
The Chemistry of Cationic Polymerization
, P.R Plesch, ed Macmillan Co.,
New York, 1963
4. D.N. Bhattacharyya, C.L Lee I Smid, and M. Szwarc,
J. Phys. Chem
,
1965
,
69
, 612
5. D.N. Bhattacharyya, I Smid, and M. Szwarc,J. Phys. Chem.,
1965
, 69, 624
6. G.T. Chen,
J. Polymer Sci., Polymer Chem. Ed.
1982
.,
20
, 2915
7. T. Keii, E. Suzuki, M. Tamura, M. Murata, and Y. Doi,
Mak.romoL Chem
.,
1982
,
183
, 2285
