Chemistry Reference
In-Depth Information
Syringe
Detector
Injection port
Chromatogram
Oven
Column
Computer
Figure 2.1 Schematic diagram of a gas chromatograph.
1.4
1.2
1
Nitrogen
Hydrogen
Helium
0.8
0.6
0.4
0.2
0 0
20
60
Average Linear Velocity (cm/s)
40
80
100
Figure 2.2 Van Deemter plot: influence of carrier gas on column efficiency (as
HETP).
detector (see Section 2.6.5). ( Note: An additional gas may be required as fuel
for the detector—for example, hydrogen and air for a flame ionisation detec-
tor; see Section 2.6.)
2.2.1 Gas Purity
As well as the choice of gas, another important quality is its purity. Gas impu-
rities would manifest themselves in the resultant chromatogram generated
 
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