Chemistry Reference
In-Depth Information
Table 2
Geometric parameters for halogen bonded complexes with phosphorus and sulfur electron donors
P
I-I
REFCODE
···
X
a
(A)
a
X
a
-Y (A)
X
a
-Y (
◦
)Mode
Compound name
B
d
···
d
···
X
a
(A)
a
X
a
-Y (A)
X
a
-Y (
◦
)Mode
REFCODE
Compound name
B
d
···
d
···
CENYEA
1,2-Bis((di-iodo)diphenylphosphino) ethane
2.471
3.148
177.34
A
JITSIO
Triphenylphosphine diiodine
2.480
3.161
178.23
A
QAMZAF
(2-Methyl-1,2-dicarba-
closo
-dodecaboranyl)-bis(isopropyl)-
2.598
3.021
177.50
A
(diiodine)phosphane
ECISIT
1-Diphenylphosphino-2-methyl-1,2-dicarbadodecaborane(10)
3.334
2.775
173.81
B
hemikis(iodine)
B
d
-
-X
+
(A)
X
+
···
X
-
(A) B
d
-
X
+
···
X
-
(
◦
)Mode
REFCODE
Compound name
FILTEZ
Bis(triphenylphosphine-iodo)-triiodine triiodide
2.399
3.507
177.39
I
FILTID
(Triphenylphosphine-iodo)-triiodine
2.394
3.551
156.79
I
LOBKOC
(Tetraiodo)-triphenylphosphite
2.367
3.389
170.28
I
1,8-Bis(tri-
p
-tolylphosphito)octaiodide
I
LOBKUI
2.361
3.345
170.77
LOBLAP
(Tetraiodo)-tris(2,4-di-
t
-butylphenyl)phosphate
2.390
3.227
170.80
I
SORPUK
Tris(2,4,6-trimethoxyphenyl)(diiodine)phosphine
2.483
3.340
174.50
I
dichloromethane solvate
I
ZEKMOR
Dimethylphenyl(diiodo)phosphorus
2.410
3.408
177.01
P
I-Br
PESJOM
···
Triphenylphosphine iodinebromide
2.461
3.062
178.06
I
P
Br-Br
JOMSEJ
···
Triphenylphosphine dibromine
2.181
3.123
177.15
I
SUHJIO
Bromo-triphenylphosphonium tribromide
2.144
3.492
151.54
I
2.134
3.549
153.89
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