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the striking similarities between XB and HB (e.g. IR and Raman spectro-
scopies [209-213], 19 F [67, 68, 213-215], 14 N [67], 1 H [216-220] and 13 C [57,
221, 222] NMR spectroscopies, NQR [223, 224], ESR [225], XPS [226], UV-vis
spectroscopy [66, 134, 171, 227, 228], dielectric polarization [229-234], calori-
metric analysis [235], GC analysis [236, 237], vapour phase pressure [238,
239]). All these techniques consistently prove the existence and the relevance
of XB also in solution, but an XB-based supramolecular chemistry in the
liquid phase still remains to be fully developed.
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