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Fig. 14
Different adamantanoid architectures formed on self-assembly of:
A
aself-
complementary tetradentate module;
B
a tetradentate XB acceptor and a bidentate XB
donor;
C
a tetradentate XB acceptor and a tetradentate XB donor
Adamantanoid architectures are formed also on the self-assembly of tetraden-
tate XB acceptors, that sit at the nodes, with bidentate XB donors, that work
as nodes spacers (e.g. in the complex 1,4-diiodooctafluorobutane/tetrakis(4-
pyridyl)pentaerythritol [195]).
The halogen-bonded 2D and 3D networks described above frequently
present large meshes. As is the case for similarly sized networks, which are
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