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Fig. 12 Examples of layered crystal packing wherein cationic layers alternate with anionic
halogen-bonded layers
From a topological point of view, the homocrystal of 1,3-di(4-pyridyl)-2,4-
di(4-iodiotetrafluorophenyl)cyclobutane, which is a self-complementary and
tetradentate module, also presents a (4,4) net [176].
An example of 3D architecture is the adamantanoid network that is formed
after various self-assembly protocols. This network is in fact present in the
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