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fractions, total mobility of metals could be enhanced by facilitated transfer of the
colloids during infiltration of runoff waters. The association between Fe and
Al-bearing phases and Cd, Cr, Zn and Cu was confirmed, just as the link between
Cu and organic matter in the <0.45 mm fraction. Mn-bearing phases were pointed
out, as the association of Ni with metallic oxy-hydroxides and siliceous particles.
This study revealed also that Pb could be more linked to particulate organic matter
than adsorbed on metallic oxy-hydroxides. These observations underscore the
need for observation of metal-bearing solids phases and characterization of
organic phases in runoff waters.
Acknowledgements This work has partially benefited from financial support of the ANR ECCO
(France).
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