Chemistry Reference
In-Depth Information
TABLE 8.17 (continued)
Analysis of Biologically Important Compounds at Carbon Paste Electrodes: Amines and Other Amino-Compounds
Analyte
Modiier
Carbon Paste
Techniques
Comments
Ref(s)
Cysteine
Cu
2
O
G(arc)/mo
CV,.LSV
Peak.at.−650.mV.(probably.reduction.of.the.
Cu(I)-SR-complex)
Borate.buffer,.pH.9.2
LOD.2.nM
[1316]
Cysteine
Co(II,III)-oxide
G/mo
FIA.(0.4.V.vs..SSE)
Catalytic.ox.;.PBS.0.1.M,.pH.7.or.NaOH.
0.1.M
[1230]
Cysteine
Cystine
RuO
2
[2714]
Cysteine
V
IV
O-salen
G/mo
CV,.LSV,.A.(0.8.V.vs..SCE)
LOD.1.7·10
−4
.M.(A);.also.for.
N
-acetylcysteine,.glutathione.and.
6-thiopurine
[1594]
Cysteine
12.molybdovanadate(V)
CILE
CV;.A.(0.4.V.vs..Ag/AgCl)
Pharmaceutical.samples
[487]
Cysteine
Poly(
N
,
N
-dimethylaniline).+.
ferrocyanide
G/p
CV,.A.(0.2.V.vs..Ag/AgCl)
LOD.6.17.×.10
−5
.M.(CV),.6.38.×.
10
−6
.M.(A)
[2715]
Cysteine
Hexacyanoferrate/SiAl-ion.
exchanger
G/hydrocarbon.
oil
CV
ox..of.cysteine
[1821]
Cysteine
Cu(II)/Co(II)-hexacyanoferrate
G/po
CV,.LSV
PBS,.pH.2,.0.1.M
LOD.5.μM
[1040]
Cysteine
Cystine
Methionine
Ru(III)-hexacyanoferrate(II).ilm
FIA
[1042]
Cysteine
Cu(II)-diethyldithiocarbamate
DPASV
[1310]
LOD.2.μM
Cysteine-glutathione
Ru(III)-diphenyldithiocarbamate
G/p
CV,.A
ox.at.+0.38.V.vs..SCE;.KNO
3
/HNO
3
,.pH.3;.
LOD.9.16.mg.L
−1
[1608]
Cysteine
Cu(II)-cyclohexylbutyrate
ASV.(
E
acc
..−0.9.V.vs..Ag/AgCl)
acc..as.Cu(I)-complex,.ox.at.0.03.V.to.
Cu(II);.LOD.2.nM
[2716]
Cysteine
Ferrocene
C/po
CV,.DPV
PBS,.pH.7.0
LOD.4.7.μM.(DPV);.in.soya.protein.
powder,.human.serum
[877]
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