Chemistry Reference
In-Depth Information
NITROGEN-BASED ORGANIC COMPOUNDS
Class
General Formula
Example
Amines
R
NH 2
NH 2
methyl amine
CH 3
Nitro compounds
R
NO 2
CH 3 CH 2 NO 2
nitroethane
Nitriles
R
CN
CN
acetonitrile
CH 3
Isocyanates
R
N
=
C
=
O
CH 3
NCO
methyl
isocyanate
O
C NH 2
Amides
CH 3 CONH 2
acetamide
R
The most important element in organic chemistry after carbon, hydrogen,
and oxygen is nitrogen. Generally, nitrogen behaves in organic compounds
as if it has a valence of three; that is, each nitrogen is bonded to three other
atoms. Amines are derivatives of ammonia (NH 3 ). Nitro compounds are
based on oxides of nitrogen, for example, nitrogen dioxide (NO 2 ), which is
also used to make nitric acid. Nitriles are derivatives of hydrogen cyanide
(HCN). Isocyanates contain the group
O and are highly reactive, for
example, with water. Amides are formed by the reaction of carboxylic acids
or their derivatives with ammonia or amines.
N
=
C
=
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