Chemistry Reference
In-Depth Information
BENZENE DERIVATIVES
CH 2
CH 2
hydrogen
CH 3
CH
CH 2
HNO 3 /H 2 SO 4
chlorine
oxygen
O
CH 2
CH 3
CH 3
CH
CH 3
NO 2
(Cl) 16
O
O
ethylbenzene
cyclohexane
isopropylbenzene
nitrobenzene
chlorobenzenes
maleic anhydride
catalyst
oxygen
hydrogen
CH
CH 2
OH
NH 2
styrene
phenol
aniline
During the 1800s, benzene was of limited commercial value, finding use
mainly as a solvent. But after the invention of the internal combustion engine
and the automobile, it was found that motors ran better when the fuel
contained benzene. This added a new economic incentive to recover all of
the benzene possible from the steel industry's coke ovens. However, just
prior to World War II, the importance of benzene as a chemical intermediate
started to be recognized. These dual incentives (gasoline and chemical inter-
mediate) led to new and improved benzene processes based on petrochem-
istry rather than coal.
 
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