Environmental Engineering Reference
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Figure 3.16 Sketches (a) intrinsic (pure) Si (b)
N-type doped Si, and (c) PN junction. Electron
energy vertically as in Figure 3.15, but wave
vector k ¼p/
electrons in P-region and p n holes in N-region,
which set the reverse current density. The
minority electrons in diffusion length L n (c,
upper left) fall down by eV B (across the junction)
in minority carrier lifetime t, creating reverse
current density J rev 2e (L n n p /t) (assuming
holes behave similar to electrons). Positive
applied bias voltage V (not shown) raises bands
on the right, as indicated by increasing
probability P for electron on the right to increase
kinetic energy toward barrier height and flow to
the left: P¼ exp(e(V B V)/k B T). Forward
current in this device is electrons from right to
left; forward bias reduces the band bending.
(Courtesy of M. Medikonda).
, is now assumed to be fixed at the
k location of the most important carriers
(usually k ¼0, but displaced for electrons in Si),
and x-axis denotes location in sample. It is seen
(b) that Fermi energy moves fromnear center of
gap in intrinsic material up toward conduction
band edge E c , with addition of donor impurities
at concentration N D . The concentration N e of
free electrons is given by Equation 3.54, but the
zero-order estimate is N e N D . (The band
density of states N C is given by Equation 3.53,
similarly for N V .) (c) shows junction formation
with energy shift eV B , with minority carriers: n p
h
where we have introduced a possible forward external bias V , seen to reduce the band
shift. Note that permittivity is expressed as k and also as e . In practice, one side, let us
assume the N-side, may be highly doped, even to produce a metallic situation as
discussed before (3.59). In this case of a one-sided junction, the width formula
simpli es (for N D large) to
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