Chemistry Reference
In-Depth Information
(phosphate-based
!
silica-based). Up to now, the choice of an OSDA to discover new
zeolites is rather serendipitous. The fluoride route was successfully used as well for the
preparation of clays free of impurities. Finally, outside of the scope of this review dealing
with the preparation of 0-, 1-, 2- and 3-D crystallized microporous materials, the fluoride
method was also profitably applied to produce ordered mesoporous silica materials (not
discussed here) [226, 227]. This came quickly after their discovery in the early 1990s
[228]. This synthetic approach was indeed advantageously used by Prouzet et al. to
synthesize, in a two-step process, spherical ordered mesoporous silica with vermicular
porous structure for membrane applications [229].
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