The Fluoride Route: A Good Opportunity for the Preparation of 2D and 3D Inorganic Microporous Frameworks - Functionalized Inorganic Fluorides - page 493

Table 16.1 (continued)

Materials Organic structure directing agent (OSDA) IZA

Codes

Channel systems
(pore openings) a

Ref.

Silicalite-2 tetrabutylammonium þ hexamethonium þ

diaminododecane or 1,1-diethyl-3,5-dimethyl-
piperidinium or 1-Butyl-1-cyclooctyl-
pyrrolidinium

MEL 3D (10 $ 10) 12,

58

Silicalite-1 tetrapropylammonium and many others MFI 3D (10 $ 10) 3

Mordenite d Na þ MOR 3D (12 $ 10) 59,

60

MCM-35 hexamethyleneimine MTF 1D (8) 61

ZSM-39 d

tetramethylammonium MTN 0D (6) 42

ZSM-23 d

1,3-diisopropyl-H-imidazol-1-ium MTT 1D (10) 62

ZSM-12 1-isopropyl-2,3-dimethyl-3H-imidazol-1-ium

and others

MTW 1D (12) 4,

12

MCM-22 hexamethyleneimine or 3-ethyl-1,3,8,8-

tetramethyl-3-azonia-bicyclo[3.2.1]octane

MWW 2 2D (10 $ 10) 12,
63

SSZ-37 4,8-ethenobenzo[1,2-c:4,5-c']dipyrrolium-

2,2,6,6-tetramethyl-1,2,3,3a,4a,5,6,7,7a,8a-
decahydro

NES 2D (10 $ 10) 12

CJS-2,
Nonasil

bis(cyclopentadienyl)cobalt(III) NON 0D (6) 42,

64

SSZ-50 2,2-diethyl-5,7,7-trimethyl-2-azonia-

bicyclo[4.1.1]octane or 3-ethyl-1,3,8,8-
tetramethyl-3-azonia-bicyclo[3.2.1]octane

RTH 2D (8 $ 8) 12,

65

Nu-1 a
RUB-10

tetramethylammonium or pyrrolidine or
N,N,N,N 0 ,N 0 ,N 0 -hexamethyl-N,N 0 -(3-oxa-
pentandiyl)-di-ammonium

RUT 0D (6) 66-

68

SSZ-73 3-ethyl-1,3,8,8-tetramethyl-3-azonia-

bicyclo[3.2.1]octane

SAS 1D (8) 69

SSZ-44 (2S,6R)-1,1-diethyl-2,6-dimethyl-piperidinium SFF 1D (10) 70

1-azonia-tricyclo[3.3.3.0 1,5 ]undecane

Sigma-2 SGT 0D (6) 12

Sodalite d Na þ SOD 0D (6) 71

1,1 0 -dimethyl-1,1 0 -butanediyl-bis-
pyrrolidinium

SSZ-75 STI 2D (10 $ 8) 72,

73

ITQ-9 1,3,3,6,6-pentamethyl-6-azonia-

bicyclo[3.2.1]octane or 1,1,2,2,6,6-
Hexamethyl-piperidinium

STF 1D (10) 74,

75

Mu-26 (6R,10S)-6,10-dimethyl-5-azonia-

spiro[4.5]decane

STF 1D (10) 76

*STO b SSZ-31 N,N,N-trimethyl-1-adamantammonium 1D (12) 12,

77

SSZ-23 N,N,N-trimethyl-1-adamantammonium STT 2D (9 $ 7) 78

1,1 0 -dimethyl-1,1 0 -hexanediyl-bis-
pyrrolidinium

-SVR e SSZ-74 3D (10 $ 10) 79,

73

Theta-1 linear mono- or di-amines or 1,3-dimethyl-4,5-

dihydro-3H-imidazol-1-ium

TON 1D (10) 12,

80

a D for dimensionality of the channel system, in parentheses are the number of T atoms delimiting the pore apertures, the
double arrows mean interconnected channels.
b The * denotes polytypic materials.
c Beta zeolite containing 85 % of polymorph B,
d Aluminosilicates.
e Interrupted framework.