Chemistry Reference
In-Depth Information
Table 22.2
Selected fluorous precursors, intermediates and ligands
Precursor (educt)
Product [Ref.]
R
f
n
-I [36]
Ar-R
f
n
[37]
Het-R
f
n
[37]
Ar-R
f
n
[33, 3
8
, 39]
R
f
n
R
2
C
6
H
2
OH, (R
f
n
R
2
C
6
H
2
O)
3
P [40]
p
-R
f
n
C
6
H
4
OH, (
p
-R
f
n
C
6
H
4
O)
3
P [41]
p
-R
f
n
C
6
H
4
Br, (
p
-R
f
n
C
6
H
4
)
3
P [41]
2,4-(R
f
n
)
2
ArOH, [2,4-(R
f
n
)
2
ArO]
3
P [42]
[R
f
n
CH
=
CH-(CH
2
)
m
]
2
-bipy [43]
ArS-R
f
n
, AlkS-R
f
n
[33]
2,4-(R
f
8
)C
6
H
3
SeC
4
H
9
[44]
R
f
n
CH
2
CH
2
I [45]
[R
f
n
CH
2
CHISi(CH
3
)
3
, R
f
n
CH
=
CH
2
[46]
R
f
n
CH
2
CH(I)CH
2
OH [47]
R
f
n
CH
2
CH
2
CH
2
OH,
n
=
6 [47]
n
=
8
[4
8
];
n
=
6,
8
, 10 [49]
R
f
n
CH
2
CH
2
(CH
2
)
m
OH,
n
=
8
,
m
=
1, 2, 3 [50]
R
f
n
CH
2
CHIOAc, R
f
n
CH
2
CH
=
O [51]
R
f
n
-Br
R
f
n
-S-R, R
=
alkyl, aryl [52]
R
f
n
-Cl
R
f
n
CH
2
CH
2
R, R
=
alkyl, CH
2
Si(CH
3
)
3
[53]
R
f
n
CH
2
CH
2
R, R
f
n
SO
2
Cl [54]
R
f
n
-CO
2
H
R
f7
C(O)CH
2
C(O)R
f7
[55]
R
f
n
CH
2
CH
2
I
R
f
n
CH
=
CH
2
[56]
(Ferrocene)(CH
2
CH
2
R
f
n
)
2
[57]
(R
f
n
CH
2
CH
2
)
2
P((
-
)menthyl) [5
8
]
(R
f
n
C
6
H
4
)
2
PCH
2
CH
2
P(C
6
H
4
R
f
n
)
2
[41]
(
m
-R
f
n
CH
2
CH
2
C
6
H
4
)
3
P [59]
[(R
f
n
CH
2
CH
2
C
6
H
4
)
2
PCH
2
-]
2
[59]
[(R
f
n
CH
2
CH
2
)
2
P(BH
3
)CH
2
-]
2
[60]
(R
f
n
CH
2
CH
2
)
3
-
n
SiMe
n
Cl,
n
=
0, 1, 2 [35]
[(R
f
n
CH
2
CH
2
)
3
-
n
SiMe
n
C
6
H
4
]
3
P,
n
=
0, 1, 2 [35]
(R
f
n
CH
2
CH
2
)
3
SiBr [61]
(R
f
n
CH
2
CH
2
)
3
SnR, R
=
Ph, Br, H [62]
[(R
f6
CH
2
CH
2
)
2
SnO]
n
[63]
R
f
8
CH
2
CH
2
OC(O)CH
=
CH
2
-
-
[(Ph
2
PC
6
H
4
)CHCH
2
)
1
-
[CH(CO
2
CH
2
CH
2
R
f
8
)CH
2
]
n
-
, fluorous polymer-supported
arylphosphine [64]
[R
f
n
CH
2
CH
2
P(C
6
H
5
)
3
]
+
I
-
Ar(CH
=
CHCH
2
R
f
n
)
x
, Ar(CH
2
CH
2
CH
2
R
f
n
)
x
[65]
R
f
8
(CH
2
)
m
I,
m
=
2-4
R
f
8
(CH
2
)
m
PH
2
,
m
=
2-4; R
f
8
(CH
2
)
m
P[(CH
2
)
m
¢
R
f
8
]
2
,
m
/
m
¢=
3/2, 2/3, 4/3, 3/4 [66]
R
f
n
CH
2
CH
2
CH
2
I
(R
f
n
CH
2
CH
2
CH
2
OAr)
3
P(O)
x
,
x
=
0, 1[67]
[
-
N(CH
2
CH
2
CH
2
R
f
n
)CH
2
CH
2
-
]
3
[4
8
]
(R
f
8
CH
2
CH
2
CH
2
)
2
NCH
3
[13]
[R
f7
CH
2
CH
2
CH
2
CH
2
]
2
bipy [6
8
]
R
f
n
CH
2
CH
2
CH
2
OTs
N(CH
2
CH
2
N(CH
2
CH
2
CH
2
R
f6
)
2
)
3
[69]
R
f7
CH
2
OH
[R
f7
CH
2
OCH
2
]
2
bipy [6
8
]
R
f
n
(CH
2
)
n
OH
R
f
n
(CH
2
)
n
OP(O)[N(CH
2
CH
2
)
2
O]
2
,
n
=
1, 3 [70]
R
f
n
CH
2
OSO
2
C
4
F
9
(R
f
n
CH
2
OAr)
3
P(O)
x
,
x
=
0, 1 [67]
R
f
n
CH
2
CH
2
OH
(R
f
n
CH
2
CH
2
O)
3
P [9]
