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In-Depth Information
this balance may well be on the side of scCO 2 in
certain cases: the polymerisation of fluorinated
monomers, leading to polymers of the Teflon brand,
is currently conducted by DuPont on a demonstra-
tion plant using scCO 2 technology and world-scale
production is planned if these studies are successful
[88]. The British company Thomas Swan Ltd has
announced plans to build a multipurpose facility
using supercritical fluids to replace conventional sol-
vents for continuous-flow heterogeneously catalysed
processes such as hydrogenations, alkylations,
acylations and etherifications [89]. If these processes
prove to be economically viable, they substantiate
once again that 'green chemistry' can help to achieve
sustainable industrial synthesis.
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