Biomedical Engineering Reference
In-Depth Information
Ru(I)-catalyzed
ortho-directed arylation
F
3
C
Pd(0)-catalyzed
indolizine direct arylation
HO
N
N
O
OMe
N
O
N
N
NC
F
3
C
Me
Me
F
Me
F
CF
3
F
GABAA agonist
122
[100]
Anacetrapib
123
[101]
SCHEME 1.31
Structures of a GABA
A
agonist and anacetrapib.
These applications further highlight the remarkable and exciting growth in the area of
C-H bond functionalization.
REFERENCES
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;
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16
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, CRC Press, Boca
Raton,
2003
.
3. For a review, see K. Godula, D. Sames,
Science 2006
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312
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4. For selected reviews that highlight these mechanistic differences, see R. H. Crabtree,
J. Chem. Soc.,
Dalton Trans. 2001
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103
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(b)L.Que,Jr.,W.B.Tolman,
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292
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Chem. Rev. 2010
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110
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1060-1081.
6. For selected examples of the use of C-H bond insertion (outer sphere mechanism) in natural
product synthesis, see (a) J. W. Bode, M. P. Doyle, M. N. Protopopova, Q.-L. Zhou,
J. Org.
Chem.
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