Chemistry Reference
In-Depth Information
Bergeat, A.; Volpi, G.G. Crossed beam studies of elementary reactions of N
and C atoms and CN radicals of importance in combustion. Faraday Discuss.
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[71] Kaiser, R.I.; Chiong, C.C.; Asvany, O.; Lee, Y.T.; Stahl, F.; Schleyer, P.v.R.;
Schaefer, H.F. Chemical dynamics of d1-methyldiacetylene (CH
3
CCCCD;
X
1
A
1
) and d1-ethynylallene (H
2
CCCH(C
2
D); X
1
A
0
) formation from reaction
of C
2
D(X
2
þ
) with methylacetylene, CH
3
CCH (X
1
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), J. Chem. Phys. 2001,
114, 3488-3496. Stahl, F.; Schleyer, P.v.R.; Kaiser, R.I.; Lee, Y.T.; Schaefer,
H.F. Reaction of the ethynyl radical, C
2
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CCH,
under single collision conditions: Implications for astrochemistry. J. Chem.
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[72] Vereecken, L.; Peeters, J.; Bettinger, H.F.; Kaiser, R.I.; Schleyer, P.v.;
Schaefer, H.F. Reaction of phenyl radicals with propyne. J. Am. Chem. Soc.
2002, 124, 2781-2789. Kaiser, R.I.; Vereecken, L,; Peeters, J.; Bettinger, H.F.;
Schleyer, P.v.; Schaefer, H.F. Elementary reactions of the phenyl radical,
C
6
H
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, with C
3
H
4
isomers, and of benzene, C
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extraterrestrial environments. Astron. Astrophys. 2003, 406, 385-391.
[73] Kaiser, R.I.; Balucani, N.; Charkin, D.O.; Mebel, A.M. A crossed beam and
ab initio study of the C
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Lett. 2003, 382, 112-119. Balucani, N.; Mebel, A.M.; Lee, Y.T.; Kaiser, R.I.
A combined crossed molecular beam and ab initio study of the reactions
C
2
(X
1
þ
g
,a
3
u
)
þ
C
2
H
2
(X
1
u
)
þ
C
2
H
4
!
n-C
4
H
3
(X
2
A
0
)
þ
H(
2
S
1/2
). J. Phys. Chem. A 2001,
105, 9813-9818.
[74] Kaiser, R.I.; Le, T.N.; Nguyen, T.L.; Mebel, A.; Balucani, N.; Lee, Y.T.;
Stahl, F.; Schleyer, P.v.R.; Schaefer III, H.F. A combined crossed molecular
beam and ab initio investigation of C
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and C
3
elementary reactions with
unsaturated hydrocarbons — pathways to hydrogen deficient radicals in
combustion flames. Faraday Discuss. 2001, 119, 51-66.
[75] Huang, L.C.L.; Lee, Y.T.; Kaiser, R.I. Crossed beam reaction of the cyanogen
radical, CN(X
2
þ
g
,a
3
þ
), with acetylene, C
2
H
2
(X
1
þ
g
): observation of cyanoace-
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[76] Huang L.C.L.; Balucani, N.; Lee, Y.T.; Kaiser, R.I.; Osamura, Y. Crossed
beam reaction of the cyano radical, CN(X
2
tylene, HCCCN(X
1
þ
), with methylacetylene: Obser-
vation of cyanopropyne and cyanoallene. J. Chem. Phys. 1999, 111, 2857-2860.
[77] Balucani, N.; Asvany, O.; Chang, A.H.H.; Lin, S.H.; Lee, Y.T.; Kaiser, R.I.;
Bettinger, H.F.; Schleyer, P.v.R.; Schaefer III, H.F. Crossed beam reaction of
cyano radicals with hydrocarbon molecules I: chemical dynamics of cyano-
benzene (C
6
H
5
CN; X
1
A
1
) and perdeutero cyanobenzene (C
6
D
5
CN; X
1
A
1
)
formation from reaction of CN(X
2
S
þ
) with benzene, C
6
H
6
(X
1
A
1g
) and d
6
-
benzene, C
6
D
6
(X
1
A
1g
). J. Chem. Phys. 1999, 111, 7457-7471.
[78] Balucani, N.; Asvany, O.; Chang, A.H.H.; Lin, S.H.; Lee, Y.T.; Kaiser, R.I.;
Bettinger, H.F.; Schleyer, P.v.R.; Schaefer III, H.F. Crossed beam reaction
of cyano radicals with hydrocarbon molecules II: chemical dynamics of
1,1-cyanomethylallene (CNCH
3
CCCCH
2
;X
1
A
1
) formation from reaction
of CN(X
2
S
þ
) with dimethylacetylene, CH
3
CCCH
3
(X
1
A
1g
). J. Chem. Phys.
1999, 111, 7472-7479.
[79] Balucani, N.; Asvany, O.; Huang, L.C.L.; Lee, Y.T.; Kaiser, R.I.; Osamura, Y.
Laboratory investigation on the formation of unsaturated nitriles in Titan's
atmosphere. Planet. Space Science 2000, 48, 447-462.
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