Synthesis of Carbynoid Materials by Chemical Dehydrohalogenation of Halogen-Containing Polymers - Polyynes: Synthesis, Properties, and Applications - page 260

Finally, poly(ethylene-alt-chlorotrifluoroethylene) was found to have an
appreciable proportion of the alternation defects, which makes complete
elimination of hydrogen halides impossible regardless of the nature of the
dehydrohalogenating agent ( Scheme 12.11 ) [18].
A possible way to overcome the hurdle of intrinsic defects could be
synthesizing strictly linear, defect-free polymers with the use of modern,
precisely controlled polymerization techniques and utilizing them as starting
materials for dehydrohalogenation.
REFERENCES
[1] Evsyukov, S.E.; Kudryavtsev, Yu.P.; Korshak, Yu.V. Chemical dehydro-
halogenation of halogen-containing polymers. Uspekhi Khimii 1991, 60(4),
764-798 (in Russian) [Russ. Chem. Rev. 1991, 60 (4), 373-390 (Engl. Transl.)].
[2] Carbyne and Carbynoid Structures. Heimann, R.B., Evsyukov, S.E., Kavan, L.,
Eds. Kluwer Academic Publishers: Dordrecht, The Netherlands, 1999.
[3] Evsyukov, S.E. Chemical dehydrohalogenation of polymers. In Carbyne and
Carbynoid Structures. Heimann, R.B., Evsyukov, S.E., Kavan, L., Eds. Kluwer
Academic Publishers: Dordrecht, The Netherlands, 1999; 55-74.
[4] Danno, T.; Murakami, K.; Ishikawa R. Preparation of carbyne-like films by
dehydrochlorination of poly(vinylidene chloride). In Electronic Properties of
Novel Materials — Science and Technology of Molecular Nanostructures: XIII
International Winterschool. Kuzmany, H., Fink, J., Mehring, M., Roth, S.,
Eds. AIP Conf. Proc. 1999, Vol. 486, 213-216.
[5] Danno, T.; Murakami, K.; Krause, M.; Kuzmany, H. Resonance Raman scat-
tering from carbyne materials. In Electronic Properties of Novel Materials —
Molecular Nanostructures: XIV International Winterschool/Euroconference.
Kuzmany, H., Fink, J., Mehring, M., Roth, S., Eds. AIP Conf. Proc. 2000,
Vol. 544, 473-476.
[6] Kijima, M.; Toyabe, T.; Shirakawa, H. Electrocatalytic dehydrofluorination of
poly(vinylidene fluoride). Chem. Lett. 1995, 24(7), 553-554.
[7] Korshak, V.V.; Kudryavtsev, Yu.P.; Korshak, Yu.V.; Evsyukov, S.E.;
Khvostov, V.V.; Babaev, V.G.; Guseva, M.B. Formation of b -carbyne by
dehydrohalogenation. Makromol. Chem. Rapid Commun. 1988, 9(3), 135-140.
[8] Evsyukov, S.E.; Kudryavtsev, Yu.P.; Korshak, Yu.V.; Khvostov, V.V.;
Babaev, V.G.; Guseva, M.B.; Korshak, V.V. Synthesis of carbyne on the
basis of poly(vinylidene halides). Vysokomolek. Soedin., Ser. A 1989, 31(1),
27-33 (in Russian) [Polym. Sci. USSR 1989, 31(1), 29-37 (Engl. Transl.)].
[9] Kijima, M.; Mukai, S.; Ohmura, K.; Shirakawa, H.; Kyotani, M. Synthesis
of conjugated polymer with carbynoid structure by dehydrochlorination of
chlorinated polyacetylene film. Synth. Met. 1999, 101(1-3), 59-60.
[10] Akagi, K.; Nishiguchi, M.; Shirakawa, H.; Furukawa, Y.; Harada, I. One-
dimensional conjugated carbyne — Synthesis and properties. Synth. Met. 1987,
17 (1-3), 557-562.
[11] Korshak, V.V.; Kudryavtsev, Yu.P.; Evsyukov, S.E.; Korshak, Yu.V.;
Khvostov, V.V.; Babaev, V.G.; Guseva, M.B. Synthesis of carbyne on the
basis of poly(vinyl chloride). Doklady Akad. Nauk SSSR 1988, 300(4), 889-892
(in Russian) [Dokl. Phys. Chem. 1988, 300(4), 510-512 (Engl. Transl.)].