Biomedical Engineering Reference
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(a)
Time (ns)
(b)
Time (ns)
Figure 4.18 (a)Orbitaldiffusionvs.time,where B z = 0Tand E x = 1Vm 1 .
(b)Orbital diffusion vs. time, where B z = 1Tand E x = 0Vm 1 .
agitation (Adair, 1991a). Mobility studies show, however, that
tiny, non-random microscopic drift velocities are observable at
the macroscopic level. Barnes (1986) reported drift velocities for
sodiumionsinsolution10 10 timesthatofitsmeanthermalvelocity,
whileCiccottiandJacucci(1975)reportedsimilarfindingsforliquid
argon at low temperatures.
Calcium ions may be examined using a hard-sphere model.
Figure 4.11a,b shows that the E field induces an acceleration
between collisions, which results in a small drift velocity and
associated positional offset to the thermal walk. The final velocity
offsetafteronecollisionperiodis qEt
/
m ,where m isthemass, q the
 
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