Chemistry Reference
In-Depth Information
Compound
Aryloxide
M-O
M-O-Ar
Ref.
[Bi(OAr)
3
]
OC
6
H
3
Me
2
-2,6
2.091 (5) (av.)
[124 (4) av.]
i
pyramidal Bi
[Bi
2
(
2
-OAr)
2
Cl
4
(THF)
2
]
2
-OC
6
H
3
Me
2
-2,6
2.211 (5), 2.463 (5)
ii
square pyramid Bi, axial Cl
[Bi
2
(
2
-OAr)
2
Cl
4
(THF)
2
]
2
-OC
6
H
2
Me
3
-2,4,6
2.187 (3), 2.497 (3)
ii
square pyramid Bi, axial Cl
[NMe
4
]
2
[Bi
2
(OAr)
6
(
-Cl)
2
]
OC
6
H
3
Me
2
-2,6
2.154 (3)
126
ii
square pyramid Bi, axial OAr
2.152 (3)
126
2.113 (3)
125
[PPh
4
]
2
[Bi(OAr)
2
Br
3
]
OC
6
H
2
Me
3
-2,4,6
2.193 (7)
129
ii
square pyramid Bi, axial OAr
2.119 (7)
128
[Et
2
Bi(
2
-OAr)]
1
2
-OC
6
H
5
2.382 (7)
iii
chiral helical chains, tbp with axial OAr,
equatorial lone pair
[Et
2
Bi(
2
-OAr)]
1
2
-OC
6
F
5
2.4105 (7)
iii
isomorphous with OPh compound
[Bi(OAr)
2
(
2
-OAr)(
6
-toluene)]
2
.2toluene
OC
6
F
5
2.088 (9), 2.147 (8)
iv,v
dimer with
-bound toluene
2
-OC
6
F
5
2.210 (8), 2.571 (7)
[Bi(OAr)
2
(
2
-OAr)(
6
-toluene)]
2
OC
6
F
5
2.089 (8), 2.136 (8)
iv
dimer with
-bound toluene
2
-OC
6
F
5
2.168 (7), 2.555 (9)
[Bi(OAr)
2
(
2
-OAr)(THF)
2
]
2
.C
6
H
14
OC
6
F
5
2.21 (1)
126
iv
dimer
2.132 (9)
126
2
-OC
6
F
5
2.198 (9), 2.75 (1)
[Bi(OAr)
2
(
2
-OAr)(THF)
2
]
2
OC
6
F
5
2.111 (3)
130
iv
dimer
2.151 (4)
130
2
-OC
6
F
5
2.245 (4), 2.661 (4)
[NaBi(
2
-OAr)
4
(THF)]
1
2
-OC
6
F
5
Bi-O-Na
vi
polymeric chain, square pyramidal Bi, basal THF
2.16 (2), 2.41 (2)
2.18 (2), 2.42 (2)
2.31 (1), 2.24 (2)
2.22 (2), 2.35 (2)
(continued overleaf )
