Metal Aryloxides - Alkoxo and Aryloxo Derivatives of Metals - page 643

Table 6.49 ( Continued )

Bond length ( A) Bond angle ( Ž )

Compound Aryloxide M-O M-O-Ar Reference

[Ga(H-tri-OAr)]Cl
octahedral Ga, one OAr protonated, not bound

Nf CH 2 2 NHCH 2 -2-OC 6 H 3 Br-4g 3 1.897 (4)

1.904 (4)

131
124

x

[f Me 3 Si 3 SigGa OAr 3 ][H 2 NC 5 H 6 Me 4 ]
two phenoxides hydrogen bonded to
tetramethylpiperidinyl cation

OC 6 H 5 1.829 (4)

1.853 (4), 1.892 (4)

xi

i H.R. Hoveyda, V. Karunaratne, S.J. Rettig, and C. Orvig, Inorg. Chem. , 31 , 5408 (1992).
ii G. Linti, R. Frey, and K. Polborn, Chem. Ber. , 127 , 1387 (1994).
iii W.M. Cleaver, A.R. Barron, A.R. McGufey, and S.G. Bott, Polyhedron , 13 , 2831 (1994).
iv M. Webster, D.J. Browning, and J.M. Corker, Acta Crystallogr. C , 52 , 2439 (1996).
v D.G. Hendershot, M. Barber, R. Kumar, and J.P. Oliver, Organometallics , 10 , 3302 (1991).
vi Shuang Liu, E. Wong, V. Karunaratne, S.J. Rettig, and C. Orvig, Inorg. Chem. , 32 , 1756 (1993).
vii P.E. Riley, V.L. Pecoraro, C.J. Carrano and K.N. Raymond, Inorg. Chem. , 22 , 3096 (1983).
viii H.R. Hoveyda, S.J. Rettig, and C. Orvig, Inorg. Chem. , 32 , 4909 (1993).
ix D.A. Moore, P.E. Fanwick, and M.J. Welch, Inorg. Chem. , 28 , 1504 (1989).
x Shuang Liu, S.J. Rettig, and C. Orvig, Inorg. Chem. , 31 , 5400 (1992).
xi G. Linti, R. Frey, W. Kostler, and H. Urban, Chem. Ber. , 129 , 561 (1996).