Chemistry Reference
In-Depth Information
centres
1.68 (2)
1.68 (2)
1.74 (2)
143
153
141
2
-OC
6
H
5
Mg-O-Al
2.12 (av.), 1.76 (av.)
Mixed aryloxy halides, alkoxides, amides, etc.
OC
6
H
2
Bu
t
3
-2,4,6
[Al(OAr)Cl
2
OEt
2
]
tetrahedral Al
1.699 (2)
153
xiii
OC
6
H
3
Bu
t
2
-2,6
[Al(OAr)Cl
2
OEt
2
]
tetrahedral Al
1.700 (2)
155
xiv
[Al(OAr)
2
H
H
2
NBu
t
]
OC
6
H
2
Bu
t
2
-2,6-Me-4
1.735 (5)
1.710 (5)
169
164
ii
OC
6
H
2
Bu
t
2
-2,6-Me-4
[Al(OAr)
2
H
OEt
2
]
1.704 (3)
1.711 (3)
165
163
ii
OC
6
H
3
Pr
i
2
-2,6
[Al(OAr)
2
(H)(THF)
2
]
tbp with axial THF
1.752 (2)
138
xv
OC
6
H
2
Bu
t
2
-2,6-Me-4
[Al(H)
2
OAr
NMe
3
]
[Al
-H
(H)(OAr)
NMe
3
]
2
monomer and dimer co-crystallize
1.762 (4)
1.774 (3)
147
134
ii
OC
6
H
2
Bu
t
2
-2,6-Me-4
[Al(OAr)
2
PhNNNPh
]
tetrahedral Al
1.689 (3)
152
xvi
viii
Shuang Liu, E. Wong, V. Karunaratne, S.J. Rettig, and C. Orvig,
Inorg. Chem.
,
32
, 1756 (1993).
ix
P.L. Gurian, L.K. Cheatham, J.W. Ziller, and A.R. Barron,
J. Chem. Soc., Dalton Trans.
, 1449 (1991).
x
E. Muller and H.-B. Burgi,
Helv. Chim. Acta
,
70
, 520 (1987).
xi
Shuang Liu, S.J. Rettig, and C. Orvig,
Inorg. Chem.
,
31
, 5400 (1992).
xii
J.A. Meese-Marktscheffel, R.E. Cramer, and J.W. Gilje,
Polyhedron
,
13
, 1045 (1994).
xiii
S. Schulz, H.W. Roesky, M. Noltemeyer, H.-G. Schmidt,
J. Chem. Soc., Dalton Trans.
, 177 (1995).
xiv
M.D. Healy, J.W. Ziller, and A.R. Barron,
Organometallics
,
11
, 3041 (1992).
xv
J.P. Campbell and W.L. Gladfelter,
Inorg. Chem.
,
36
, 4094 (1997).
xvi
J.T. Leman, J. Braddock-Wilking, A.J. Coolong, and A.R. Barron,
Inorg. Chem.
,
32
, 4324 (1993).
(
continued overleaf
)
