Chemistry Reference
In-Depth Information
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Ref.
[Cu
2
-OAr
]
4
planar Cu
4
O
4
core, 2-coord. Cu
2
-OC
6
H
3
Ph
2
-2,6
1.834 (7) - 1.865 (7)
i
3
-OC
6
H
4
-
2
-CH
2
CH
D
CH
2
-2
[Cu
2
-OAr
]
4
distorted cubic Cu
4
O
4
core, 4-coord. Cu
1.980 (5), 1.927 (5)
2.747 (5)
ii
OC
6
H
3
2
0
-py-Bu
t
-4)-2
2
-OC
6
H
3
2
0
-py-Bu
t
-4)-2
[Cu
2
-OAr
OAr
]
2
tbp Cu with axial O and
2
-O
1.889 (2)
1.915 (1), 2.193 (2)
122
iii
[Cu(OAr)
2
imidazole
2
]
.
H
2
O
all trans
, Cl bound
OC
6
H
2
Cl
3
-2,4,6
1.97 (1)
130
iv
[Cu(OAr)
2
N
-methylimidazole
2
]
all trans
, Cl bound
OC
6
H
3
Cl
2
-2,6
1.942 (4)
126
v
[(THF)(tfd)Cu
2
-OAr
2
Cu(tfd)(THF)]
tfd D 1,1,1-trifluoro-acac, square
pyramidal Cu, axial THF
2
-OC
6
F
5
1.952 (3), 1.960 (4)
vi
[Cu(OAr)
2
]
square planar Cu,
trans
CuO
2
N
2
,
chelating OAr
OC
6
H
3
Ph-4-CH
2
NMe
2
-2
1.884 (3)
1.897 (3)
127
118
vii
[Cu(OAr)
2
]
square planar Cu,
trans
CuO
2
N
2
,
chelating OAr
OC
6
H
3
Ph-4-CH
2
NEt
2
-2
1.898 (2)
119
viii
[Cu
2
-OAr
O
2
CMe
]
2
5-coord. Cu, bidentate acetate,
chelating OAr
2
-OC
6
H
3
Ph-4-CH
2
NMe
2
-2
1.926 (2), 1.971 (2)
vii
[Cu
2
-OAr
O
2
CMe
HOMe
]
2
5-coord. Cu, monodentate acetate,
chelating OAr
2
-OC
6
H
3
Ph-4-CH
2
NMe
2
-2
1.987 (5), 1.985 (5)
vii
[Cu
2
2
-OAr
2
2
-O
2
CMe
][PF
6
]
square pyramidal Cu, axial
2
-O
2
-OC
6
H
4
2
0
-1,10-phen)-2
1.942 (2), 1.889 (3)
ix
(
continued overleaf
)
