Chemistry Reference
In-Depth Information
Compound
Aryloxide
M-O
M-O-Ar
Ref.
[Pd(OAr)
2
]
trans
-O(Ar)
OC
6
H
4
2
0
py
-2
1.979 (2)
117
i
[(bipy)Pd(OAr)
2
]
square planar Pd
OC
6
H
5
1.996 (7)
1.983 (6)
121
120
ii
[(bipy)Pd(OAr)
2
]
square planar Pd
OC
6
F
5
2.013 (3)
2.013 (4)
123
125
ii
[(TMEDA)Pd(OAr)(Me)]
square planar Pd
OC
6
H
5
2.024 (3)
123
iii
[(TMEDA)Pd(OAr)(Me)](HOAr)
square planar Ph, hydrogen bonded HOAr
OC
6
H
5
2.037 (2)
122
iii
[(TMEDA)Pd(OAr)(Me)]
square planar Pd
OC
6
H
4
NO
2
-4
2.029 (4)
126
iii
[(TMEDA)Pd(OAr)(Me)](HOAr)
square planar Ph, hydrogen bonded HOAr
OC
6
H
4
NO
2
-4
2.043 (2)
125
iii
trans
-[Pd(OAr)(H)
PCy
3
2
]
HOAr
square planar Pd, hydrogen bonded HOAr
OC
6
H
5
2.135 (2)
121
iv, v
trans
-[Pd(OAr)(H)
PCy
3
2
]
HOAr
square planar Pd, hydrogen bonded HOAr
OC
6
F
5
2.181 (2)
126
iv, v
trans
-[Pd(OAr)Me
PMe
3
2
]
square planar Pd
OC
6
H
5
2.106 (3)
127
vi
trans
-[Pd(OAr)Me
PMe
3
2
]
HOAr
square planar Pd, hydrogen bonded HOAr
OC
6
H
5
2.134 (3)
122
vi
trans
-[(Pd(OAr)Me
PMe
3
2
]
CF
3
CHPhOH
square planar Pd, hydrogen bonded alcohol
OC
6
H
5
2.107 (2)
124
vi
[(bipy)Pd(OAr)fOCH
CF
3
2
g](HOAr)
square planar Pd, hydrogen bonded HOAr
OC
6
H
5
1.997 (5)
120
vii
trans
-[Pd(OAr)
2
pyrrolidine
2
]
square planar Pd, intermolecular hydrogen bonding
between ArO and pyrrolidine
OC
6
H
5
2.003 (2)
121
viii
trans
-[Pd(OAr)
2
(pyrrolidine)
2
]
HOAr
2
square planar Pd, two hydrogen bonded HOAr
OC
6
H
5
2.018 (2)
120
viii
