Chemistry Reference
In-Depth Information
Table 6.34
(
Continued
)
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Reference
[
H
2
Ru
6
CO
16
2
-O-
2
-C
6
H
3
OMe-4)]
raft cluster, metallated C bridges two metals,
phenoxy ring
-binds to another
2
-O-
2
-C
6
H
3
OMe-4
2.132 (5), 2.159 (5)
xvi
[
Ph
3
PA u
(H)Ru
6
CO
16
2
-O-
2
-C
6
H
3
OMe-4
]
raft cluster, metallated C bridges two metals,
phenoxy ring
-binds to another
2
-O-
2
-C
6
H
3
OMe-4
2.14 (2), 2.15 (2)
xvi
[Ru
3
CO
8
2
-
2
-OAr
2
]
aryloxides both chelate through Cl and bridge
one edge of triangular cluster
2
-OC
6
H
4
Cl-2
2.110 (4), 2.163 (4)
2.093 (4), 2.161 (4)
xvii
[Ru
4
3
-OAr
2
2
-Cl
2
CO
10
]
3
-OC
6
H
5
2.144 (1) - 2.218 (1)
xviii
[Ru
4
3
-OAr
2
2
-OAr
2
-Cl
CO
10
]
two molecules
2
-OC
6
H
4
OMe-2
3
-OC
6
H
4
OMe-2
2.029 (7) - 2.230 (6)
2.121 (7) - 2.218 (7)
xix
xvi
M.P. Cifuentes, T.P. Jeynes, M.G. Humphrey, B.W. Skelton, and A.H. White,
J. Chem. Soc., Dalton Trans.
, 925 (1994).
xvii
D.J. Darensbourg, B. Fontal, S.S. Chojnacki, K.K. Klausmeyer, and J.H. Reibenspies,
Inorg. Chem.
,
33
, 3526 (1994).
xviii
S. Bhaduri, N. Sapre, K. Sharma, P.G. Jones, and G. Carpenter,
J. Chem. Soc., Dalton Trans.
, 1305 (1990).
xix
T.P. Jeynes, M.P. Cifuentes, M.G. Humphrey, G.A. Koutsantonis, and C.L. Raston,
J. Organomet. Chem.
,
476
, 133 (1994).
