Chemistry Reference
In-Depth Information
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Reference
[NEt
4
][Re
3
-H
3
-OAr
CO
10
]
triangular cluster
2
-OC
6
H
5
2.176 (5), 2.176 (5)
x
[NEt
4
][Re
3
-OAr
3
(CO)
6
]
confacial bi-octahedron
2
-OC
6
H
5
2.11 (1) - 2.15 (1)
x
[NEt
4
][Re
-OH
-OAr
2
CO
6
]
confacial bi-octahedron
2
-OC
6
H
5
2.156 (8) (av.)
xi
[(Bu
t
N
Br(mes)Re
-NBu
t
-O
Re
OC
6
H
2
Me
2
-
CH
2
NBu
t
]
cyclometallated mesityl oxide
OC
6
H
2
Me
2
-CH
2
1.96 (1)
117
xii
[NBu
t
4
][Re(O)Cl(OAr)]
trans
ArO-Re
D
O
OC
6
H
4
PPh
2
-2
2.016 (6)
127
xiii
[AsPh
4
][Re(O)
2
(OAr)
2
].0.5EtOH.0.5Me
2
CO
Trans O
D
Re
D
O,
cis
-O(Ar)
OC
6
H
4
PPh
2
-2
2.12 (1)
2.13 (1)
122
119
xiii
[Re(O)Cl(OAr)
2
]
cis
-O(Ar),
trans
ArO-Re
D
O
OC
6
H
4
PPh
2
-2
2.013 (9)
2.032 (9)
124
127
xiii, xiv
[Re(O)Cl(OAr)
HNC
6
H
4
PPh
2
-2)]
trans
ArO-ReDO
OC
6
H
4
PPh
2
-2
2.04 (1)
129
xiii
fac-cis
-[Re(O)(di-OAr)(OAr)]
cis
-P,P
OC
6
H
4
PPh
2
-2
OC
6
H
4
-2
2
PPh
1.994 (3)
2.050 (3)
2.026 (3)
123
119
127
xv
fac-cis
-[Re(NPh)(di-OAr)Cl(PPh
3
)].2CHCl
3
cis
-P,P
OC
6
H
4
-2
2
PPh
2.050 (3)
2.050 (3)
122
126
xv
x
T. Beringhelli, G. Ciani, G. D'Alfonso, A. Sironi, and M. Freni,
J. Chem. Soc, Dalton Trans.
, 1507 (1985).
xi
Chenghua Jiang, Yuh-Sheng Wen, Ling-Kang Liu, T.S.A. Hor, and Yaw Kai Yan,
Organometallics
,
17
, 173 (1998).
xii
A. Gutierrez, G. Wilkinson, B. Hussain-Bates, and M.B. Hursthouse,
Polyhedron
,
9
, 2081 (1990).
xiii
C. Bolzati, F. Tisato, F. Refosco, G. Bandoli, and A. Dolmella,
Inorg, Chem.
,
35
, 6221 (1996).
xiv
F. Loiseau, Y. Lucchese, M. Dartiguenave, F. Belanger-Gariepy, and A.L. Beauchamp,
Acta Crystallog. C
,
52
, 1968 (1996).
xv
Hongyan Luo, I. Setyawati, S.J. Rettig, and C. Orvig,
Inorg. Chem.
,
34
, 2287 (1995).
