Chemistry Reference
In-Depth Information
Bond length ( A)
Bond angle
Ž
Compound
Aryloxide
M-O
M-O-A
Reference
[W
OC
6
HPh
3
-
6
-C
6
H
5
OAr
PMe
3
]
OC
6
HPh
4
-2,3,5,6
1.990 (3)
130
xxxviii
OC
6
HPh
3
-
6
-C
6
H
5
2.028 (3)
118
[W
OC
6
HPh
3
-
6
-C
6
H
5
OAr
PBu
3
]
OC
6
HPh
4
-2,3,5,6
1.987 (4)
134
xxxviii
OC
6
HPh
3
-
6
-C
6
H
5
2.025 (4)
118
[W
OC
6
HPh
3
-
6
-C
6
H
5
OAr
PMe
2
Ph
]
C
6
HPh
4
-2,3,5,6
1.966 (9)
131
xxxix
OC
6
HPh
3
-
6
-C
6
H
5
2.022 (9)
120
[W
OC
6
HPh
3
-
6
-C
6
H
5
OC
6
HPh
3
-
2
-C
6
H
9
PMe
2
Ph
]
chelating arene and cyclohexene rings
OC
6
HPh
3
-
6
-C
6
H
5
OC
6
HPh
3
-
2
-C
6
H
9
2.130 (4)
2.066 (4)
125
118
xxxix
[W
OC
6
H
3
Ph-
6
-C
6
H
5
H
PMePh
2
2
]
OC
6
H
3
Ph-
6
-C
6
H
5
2.163 (9)
119
xl
[W
OC
6
H
3
Ph-
6
-C
6
H
5
(Cl)
PMe
2
Ph
2
]
OC
6
H
3
Ph-
6
-C
6
H
5
2.128 (4)
122
xl
[W
OC
6
H
3
Ph-
6
-C
6
H
5
(Cl)(dppm)]
OC
6
H
3
Ph-
6
-C
6
H
5
2.135 (8)
121
xl
[NEt
4
]
3
[(CO)
3
W
2
-OAr
3
W(CO)
3
]
2
-OC
6
H
5
2.210 (6) - 2.234 (5)
xli
confacial bis-octahedral anion
[NEt
4
][W(OAr)(CO)
5
]
OC
6
H
3
Ph
2
-2,6
2.165 (9)
2.175 (9)
128
124
xlii
[NEt
4
][(CO)
5
W
-OAr
Cr(CO)
3
]
2
-
6
-C
6
H
5
2.35 (3)
128
xliii
[NEt
4
][W(OAr)(CO)
4
PMePh
2
]
OC
6
H
5
2.191 (6)
130
xlii
[NEt
4
][W(OAr)(CO)
5
]
OC
6
H
5
2.182 (19)
2.205 (21)
131
134
xliv
[NEt
4
][W(OAr)(CO)
5
]0
.
5
H
2
O
OC
6
H
5
2.224 (15)
132
xliv
[NEt
4
][W(OAr)(CO)
5
]0
.
5
H
2
O
OC
6
H
5
2.191 (14)
130
xliv
[W
OC
6
HPh
3
-
1
-C
6
H
4
(OAr)
1
-
PhN
D
CHPh
PhNCH
3
Ph
]
tbp, axial O (cyclometallated OAr)
and N (amide)
OC
6
HPh
4
-2,3,5,6
OC
6
HPh
3
-
1
-C
6
H
4
1.922 (4)
1.961 (4)
166
131
xlv
