Chemistry Reference
In-Depth Information
Table 6.27
(
Continued
)
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Reference
[(tpp)Cr(OAr)(THF)]
OC
6
H
5
1.94 (1)
x
meso-tetraphenylporphyrin, 6-coord. Cr
Di- and poly-aryloxides
[Cr
4
-F
4
(di-OAr)
4
]
fCH
2
NH
CH
2
-2-OC
6
H
4
g
2
1.919 (3)
126
xi
tetramer with linear Cr-F-Cr, 6-coord. Cr
1.925 (3)
1.933 (3)
1.886 (3)
123
126
129
[fCr(di-OAr)g
2
-F
-OEt
]
c
-(CH
2
6
fNH-2-OC
6
H
3
Bu
t
-4g
2
1.930 (4)
1.954 (3)
125
126
xi
[Cr
-di-OAr)Cl]
2
-fCH
2
NH
CH
2
-2-OC
6
H
4
g
2
1.903 (2)
133
xi
6-coord. Cr, one OAr bridging
2.022 (2), 2.024 (2)
[Cr
2
-di-OAr
2
(py)
4
]
fCH
2
NHCO
2-OC
6
H
2
Cl
2
-4,6
g
2
1.916 (8)
126
xii
6-coord. Cr, two Cr centres linked by di-OAr
1.952 (8)
127
[Cr(tri-OAr)]
2
[Mn
OH
2
6
][BPh
4
]
2
c
-
CH
2
6
fNCH
2
C
6
H
3
Bu
t
-4-Og
3
1.956 (5)
1.945 (5)
1.949 (5)
130
129
128
xiii
c
-
CH
2
6
fNCH
2
-2-OC
6
H
3
Bu
t
-4g
3
[Cr(tri-OAr)]
1.937 (5)
128
xiv
1,4,7-tricyclononane with N-pendant aryloxides,
fac
-arrangement of O and N donor atoms
x
A.L. Balch, L. Latos-Grazynski, B.C. Noll, M.M. Olmstead, and E.P. Zovinka,
Inorg. Chem.
,
31
, 1148 (1992).
xi
A. Bottcher, H. Elias, J. Glerup, M. Neuburger, C.E. Olsen, H. Paulus, J. Springborg, and M. Zehnder.
Acta Chem. Scand.
,
48
, 967 (1994).
xii
T.J. Collins, B.D. Santarsiero, and G.H. Spies,
J. Chem. Soc., Chem. Commun.
, 681 (1983).
xiii
U. Auerbach, C. Stockheim, T. Weyhermuller, K. Wieghardt, and B. Nuber,
Angew. Chem., Int. Ed. Engl.
,
32
, 714 (1993).
xiv
U. Auerbach, T. Weyhermuller, K. Wieghardt, B. Nuber, E. Bill, C. Butzlaff, and A.X. Trautwein,
Inorg. Chem.
,
32
, 508 (1993).
