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[V(O)(di-OAr)]
6-coord. V, both OAr, both N and alkoxide
bound
OC 6 H 4 fCH 4 NH CH 2 2 N 2-OC 6 H 4 CH 2 2 Og-2
1.910 (7)
1.840 (3)
136
138
xiii
c - CH 2 6 fNCH 2 -2-OC 6 H 3 Bu t -4g 3
[V(tri-OAr)][BPh 4 ]
octahedral V
1.834 (5)
1.809 (5)
1.831 (4)
136
137
137
xxviii
[V(tetra-OAr)]
octahedral V
2-OC 6 H 4 CH 2 2 N CH 2 2 N CH 2 C 6 H 4 O-2 2
1.848 (4)
1.877 (4)
1.872 (4)
1.853 (4)
138
131
129
140
xxix
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1782 (1993).
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xxv A.S. Borovik, T.M. Dewey, and K.N. Raymond, Inorg. Chem. , 32 , 413 (1993).
xxvi A. Neves, A.S. Ceccato, S.M.D. Erthal, I. Vencato, B. Nuber, and J. Weiss, Inorg. Chim. Acta , 187 , 119 (1991).
xxvii A. Neves, I. Vencato, and Y.P. Mascarenhas, Acta Crystallog. C , 50 , 1417 (1994).
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