Chemistry Reference
In-Depth Information
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Ref.
[CpTi(OAr)(Cl)]
2
-O
OC
6
H
3
Pr
i
2
-2,6
1.80 (1)
147
lxxvii
OC
6
H
3
Pr
i
2
-2,6
[CpTi(OAr)
2
]
2
-S
1.84 (1)
1.80 (1)
1.80 (1)
1.81 (1)
151
153
153
149
lxxvii
OC
6
H
3
Pr
i
2
-2,6
[CpTi(OAr)]
2
-S
-S
2
1.813 (7)
1.816 (7)
150
159
lxxvii
[Cp
Ł
Ti
OAr
S
5
]
OC
6
H
3
Pr
i
2
-2,6
1.795 (6)
167
lxxvii
OC
6
H
3
Pr
i
2
-2,6
[fCpTi(OAr)
-SPh
g
2
]
1.828 (2)
1.822 (2)
161
155
lxxvii
[CpTi(OAr)
2
-O
]
4
OC
6
H
2
Me
3
-2,4,6
1.841 (3)
1.840 (4)
1.815 (4)
1.818 (4)
145
142
154
147
lxxviii
Di- and poly-aryloxides
[Ti
di-OAr
Cl
2
]
CH
2
2-OC
6
H
3
Bu
t
-6-Me-4
2
1.742 (4)
1.761 (4)
156
144
lxxix
CH
2
2-OC
6
H
3
Bu
t
-6-Me-4
2
[Ti
di-OAr
Me
2
]
1.799 (3)
146
lxxix
CH
2
2-OC
6
H
3
Bu
t
-6-Me-4
2
[Ti
di-OAr
BH
4
2
]
1.761 (3)
1.791 (3)
159
143
lxxx
N
2-OC
6
H
3
Bu
t
2
-4,6
2
[Ti
di-OAr
2
]
6-coord. Ti
1.899 (?)
1.872 (?)
122
126
lxxxi
[
di-OAr
OPr
i
Ti
2
-OPr
i
2
Ti
OPr
i
di-OAr
]
6-coord. Ti
S
OC
6
H
2
Me-4-Bu
t
-6
2
1.899 (2)
1.885 (2)
133
132
lxxxii
S
OC
6
H
2
Me-4-Bu
t
-6
2
[Ti
di-OAr
Cl
C
6
H
4
CH
2
NMe
2
]
1.831 (3)
136
lxxxiii
6-coord. Ti
1.879 (3)
135
lxxxii
