Chemistry Reference
In-Depth Information
Table 6.21
(
Continued
)
Bond length ( A)
Bond angle (
Ž
)
Compound
Aryloxide
M-O
M-O-Ar
Ref.
OC
6
H
3
Pr
i
2
-2,6
[Ti(OAr)
2
2
-PhNDNPh)(py)
2
]
two independent molecules, mono-
2
-azobenzene
1.836 (5)
1.852 (6)
1.845 (5)
169
169
176
lvi
[Ti
4
3
-O
4
(OAr)
4
f
-(CO)
9
Co
3
3
-CCO
2
g
4
]
OC
6
H
5
1.788 (7) (av.)
145 - 165
xxxv
OC
6
H
3
Pr
i
2
-2,6
[Ti(OAr)
2
O
4-pyrrolidinopyridine
2
]
tbp Ti,
trans
axial py ligands
1.863 (6)
1.879 (6)
167
172
xxxvi
[Ti(OAr)
2
D
NPh
4-pyrrolidinopyridine
2
]
tbp Ti,
trans
axial py ligands
OC
6
H
3
Pr
i
2
-2,6
1.867 (3)
1.880 (3)
174
172
xxxi
[Ti(OAr)
2
DNC
6
H
3
Me
2
-2,6)(py)
2
]
OC
6
H
3
Pr
i
2
-2,6
xxxvii
[Ti(OAr)
2
-NBu
t
]
2
OC
6
H
3
Pr
i
2
-2,6
xxxvii
OC
6
H
3
Pr
i
2
-2,6
[Ti
2
-O
OAr
2
4-pyrrolidinopyridine
]
2
1.833 (2)
1.817 (2)
176
156
xxxviii
[Ti(OAr)
2
D
NPh
(3,4,7,8-Me
4
-1,10-phen)]
OC
6
H
3
Ph
2
-2,6
1.882 (3)
1.931 (3)
150
125
xxxi
Non-Cp organometallic aryloxides
[Ti(OAr)
2
(Ph)
2
]
tetrahedral Ti
OC
6
H
3
Ph
2
-2,6
1.794 (3)
1.797 (3)
153
162
xxxix
[Ti(OAr)
3
CH
2
SiMe
3
]
tetrahedral Ti
OC
6
H
3
Ph
2
-2,6
1.806 (2)
1.802 (2)
1.797 (2)
179
164
170
xxxix
