Chemistry Reference
In-Depth Information
[Nd
OC
6
H
3
Ph-
6
-C
6
H
5
OC
6
H
3
Ph-
1
-C
6
H
5
OAr
]
pyramidilized Nd due to
6
-C
6
H
5
interaction, also close
1
-C
6
H
5
interaction
OC
6
H
3
Ph
2
-2,6
OC
6
H
3
Ph-
1
-C
6
H
5
OC
6
H
3
Ph-
6
-C
6
H
5
2.140 (3)
2.174 (3)
2.193 (5)
166
150
139
[Nd
OC
6
H
3
Ph-
3
-C
6
H
5
OAr
2
THF
]
trigonal pyramid with weaker basal
3
-C
6
H
5
interaction
OC
6
H
3
Ph
2
-2,6
2.186 (2)
2.160 (2)
166
169
xxvi
OC
6
H
3
Ph-
3
-C
6
H
5
2.233 (3)
143
[Na
2
-OAr
3
Nd(OAr)]
two independent molecules; in one Na is
2
-,
2
-, and
1
-bound to ortho-Ph groups, in the other it is
2
-,
2
-, and
2
-bound
OC
6
H
3
Ph
2
-2,6
2.208 (4)
2.236 (4) - 2.244 (5)
2.181 (6)
2.199 (6) - 2.278 (4)
156
xiv, xxvii
2
-OC
6
H
3
Ph
2
-2,6
157
[Na(diglyme)
2
][Nd(OAr)
4
]
distorted tetrahedral anion
OC
6
H
3
Ph
2
-2,6
2.175 (4)
2.207 (4)
2.176 (4)
2.191 (4)
177
167
164
169
xxvii
[Cp
2
Nd(OAr)
THF
2
]
distorted tbp, axial THF
OC
6
H
3
Ph
2
-2,6
2.239 (8)
180
xxix
[Nd(OAr)
3
Me
4
urea
3
]
distorted tricapped trigonal prism
OC
6
H
2
NO
2
3
-2,4,6
2.384 (5), 2.342 (5),
2.382 (5)
xxx
xx
C. Barberato, E.E. Castellano, G. Vicentini, P.C. Isolani, and M.I.R. Lima,
Acta Crystallogr. C
,
50
, 351 (1994).
xxi
L.F. Delboni, G. Oliva, E.E. Castellano, L.B. Zinner, and S. Braun,
Inorg. Chim. Acta
,
221
, 169 (1994).
xxii
D.M. Barnhart, D.L. Clark, J.C. Gordon, J.C. Huffman, R.L. Vincent, J.G. Watkin, and B.D. Zwick,
Inorg. Chem.
,
33
, 3487 (1994).
xxiii
Liqin Chen, S.R. Breeze, R.J. Rousseau, Suning Wang, and L.K. Thompson,
Inorg. Chem.
,
34
, 454 (1995).
xxiv
S. Daniele, L.G. Hubert-Pfalzgraf, and J. Vaissermann,
Polyhedron
,
14
, 327 (1995).
xxv
J.M. Harrowfield, Lu Weimin, B.W. Skelton, and A.H. White,
Aust. J. Chem.
,
47
, 321 (1994).
xxvi
G.B. Deacon, Tiecheng Feng, B.W. Skelton, and A.H. White,
Aust, J. Chem.
,
48
, 741 (1995).
xxvii
G.B. Deacon, T. Feng, P.C. Junk, B. W. Skelton and A.H. White,
Chem. Ber.
,
130
, 851 (1997).
xxviii
G.B. Deacon, T. Feng, P.C. Junk, B. W. Skelton and A.H. White,
J. Chem. Soc., Dalton Trans.
, 1181 (1997).
xxix
G.B. Deacon, S. Nickel and E.R.T. Tiekink,
J Organomet. Chem.
,
409
, C1 (1991).
xxx
C. Barberato, E.E. Castellano, G. Vicentini, P. C. Isolani and M.I.R. Lima,
Acta Crystallogr. C,
50
, 351 (1994).
(continued overleaf )
