Chemistry Reference
In-Depth Information
Bond length ( A)
Bond angle
Ž
Compound
Aryloxide
M - O
M - O - Ar
Reference
[Cu
2
-OAr
CO
]
4
tetrahedral Cu held by O bridges
2
-2Me-8-quin
2.01 (2) - 2.08 (2)
lxx, lxxi
[Cu
2
2
-OAr
2
(dppm)]
distorted trigonal pyramid about Cu
2
-2Me-8-quin
2.141 (4) - 2.336 (6)
lxxi
[Cu(OAr
PPh
3
2
]
tetrahedral Cu
2Me-8-quin
2.088 (14)
108
lxxi
[Cu(OAr)].3H
2
O
5-SO
4
-8-quin
1.952 (3)
110
lxxii
[Au(OAr)(PPh
3
)].0.5H
2
O
8-quin
2.373 (?)
112
lxxiii
2.44 (?)
110
[Au(OAr)(PPh
3
)].H
2
O
8-quin
2.502 (?)
109
lxxiii
[Au(OAr)(Me
2
NCH
2
C
6
H
4
)][BF
4
]
8-quin
2.067 (6)
111
lxxiv
[Zn(OAr)
2
OH
2
2
]
8-quin
2.05 (?)
114
lxxv
[Zn(OAr)
2
OH
2
2
]
8-quin
2.066 (?)
111
lxxvi
[Zn
4
OAr
8
]
8-quin
2.020 (4)
112
lxxvii
1.965 (4)
107
2
-8-quin
2.176 (4), 2.074 (4)
[PhHg
2
-OAr
2
HgPh]
loose dimer
2
-2Me-8-quin
2.16 (1), 2.79 (1)
lxxviii
[Hg(OAr)Ph]
intermolecular Hg-O D 3
.
34 (4) ( A)
8-quin
2.19 (4)
2.15 (4)
120
121
lxxviii
[Hg(OAr)Ph]
8-quin
2.06 (2)
121
lxxviii
second form, intermolecular
Hg-O D 3
.
37 (1) ( A)
lxxix
[
OAr
2
Al
-O
Al(OAr)
2
]
2Me-8-quin
1.817 (5)
117
lxxx
linear Al-O-Al bridge, pseudo-tbp Al, axial N
1.809 (5)
118
1.819 (5)
116
1.804 (5)
118
