Chemistry Reference
In-Depth Information
Bond length ( A)
Bond angle
Ž
Compound
Aryloxide
M - O
M - O - Ar
Reference
[Nb(O)(OAr)
3
]
8-quin
2.047 (3)
125
xvii
2.055 (3)
124
2.055 (3)
124
2.058 (3)
125
[Cr
NBu
t
OAr
2
Cl]
.
0
.
5Et
2
O
8-quin
1.922 (8)
115
xviii
6-coord. Cr,
trans
O, Cl
trans
to NBu
t
1.920 (9)
116
[Mo(O)
2
(OAr)
2
]
8-quin
1.98 (2)
125
xix, xx, xxi
[Mo(O)(OAr)
2
NNMe
2
]
8-quin
2.019 (8)
118
xxii
cis
O(quin), hydrazido
cis
to oxo
2.123 (7)
117
[H
2
quin][Mo(O)(OAr)Cl
3
]
8-quin
2.039 (5)
121
xxiii
[W(OAr)
4
]
.
C
6
H
6
5Br-8-quin
2.070 (9)
121
xxiv
8-coord. W
2.066 (9)
123
2.071 (11)
120
2.052 (10)
122
[W(OAr)Cl(CO)
3
PPh
3
]
7-coord. W
5,7Cl
2
-8-quin
2.120 (5)
117
xxv
[W(OAr)
2
(CO)
2
PPh
3
]
.
CH
2
Cl
2
5,7Cl
2
-8-quin
2.096 (7)
118
xxv
7-coord. W
2.106 (7)
118
mer
-[Mn(OAr)
3
].MeOH
8-quin
1.905 (7)
116
xxvi
1.916 (7)
118
1.924 (7)
119
mer
-[Mn(OAr)
3
].0.5HexOH
8-quin
1.908 (5)
118
xxvi
1.921 (5)
115
1.917 (5)
118
[(OAr)(O)
2
MeRe
-O
Re(OAr)(O)
2
Me]
8-quin
2.017 (4)
122
xxvii
linear Re - O - Re, Octahedral Re
xxviii
cis
-[Tc(O)(OAr)
2
Cl]
2Me-8-quin
1.948 (3)
116
xxix
6-coord. Tc
1.994 (3)
120
