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N
OH
N
N
H
N
N
HN
Cl
OH
HO
Cl
Cl
OH
(A)
(B)
Me
HO
N
N
OH
NH
OH HN
HO
OH
Me
OH
HO
Me
(C)
(D)
NH
OH
HN
Me
CMe 3
Me 3 C
CMe 3
OH
OH
HO
OH
HO
OH
Me 3 C
CMe 3
CMe 3
(E)
Scheme 6.7
3
SYNTHESIS OF METAL ARYLOXIDES
There are a large number of synthetic routes to metal aryloxides. The synthetic strategy
that is adopted depends largely on the available metal precursors as well as the nature of
the ligand that is being used. Many of the synthetic methods used for simple aryloxide
derivatives in nonprotic solvents are identical to those used for the corresponding metal
alkoxides.
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