Chemistry Reference
In-Depth Information
3R
0
OH
!Ln
OR
0
3
C 3
MeSi
2
NH "
Ln D Y, R
0
D CEt
3
343
Ln D Ce, R
0
D CBu
t
344
3
5R
0
OH (excess)
!
3
[Ln
3
OR
0
9
]
R
0
OH
2
C 3
Me
3
Si
2
NH "
Ln D Y, La, R
0
D Bu
t
,Am
t
345
3HOCBu
t
3
, hexane
!CefN
SiMe
3
2
g
3
C 3
Me
3
Si
2
NH
150
Ž
C, vacuum
"
3Me
2
CDCH
2
!
2
[Ce
3
OCHBu
t
2
2
-OCHBu
t
2
]
2
Ln D Ce
344
3HOCPh
3
, toluene
!
2
[La
OCPh
3
2
-OCPh
3
]
2
C 3
Me
3
Si
2
NH "
Ln D La
346
3HOCBu
t
3
![Nd
OCBu
t
3
3
CH
3
CN
2
] C 3
Me
3
Si
2
NH "
hexane CH
3
CN
Ln D Nd
347
3HOCHPr
i
2
!
2
[Nd
2
OCHPr
i
2
6
thf
2
] C 6
Me
3
Si
2
NH "
hexane/THF
C
5
H
5
N
excess
!
THF
1
2
[Nd
2
OCHPr
i
2
6
NC
5
H
5
2
]
Ln D Nd
348
LnfN
SiMe
3
2
g
3
3HOCH
CF
3
2
(excess)
!
2
[ScfOCH
CF
3
2
g
3
NH
3
2
]
2
C 3
Me
3
Si
2
NH "
benzene
Ln D Sc
349
3HOCMe
CF
3
2
(excess)
!
n
[LnfOCMe
CF
3
2
g
3
NH
3
x
]
n
C 3
Me
3
Si
2
NH "
benzene
Ln D Y,
349a
n
D 0,
x
D 3
Ln D La,
349b
n
D 2,
x
D 1or2
Ln D Pr,
349b
n
D 2,
x
D 2
Ln D Eu,
349b
n
D 2,
x
D 1
3HOR
f
![Ln
OR
f
3
thf
3
] C 3Me
3
Si
2
NH "
THF
Ln D Y,
349
R
f
D CH
CF
3
2
Ln D Y,
349a
La, Eu,
349b
R
f
D CMe
CF
3
2
3HOCMe
CF
3
2
![LnfOCMe
CF
3
2
g
3
Et
2
O
0
.
33
] C 3
Me
3
Si
2
NH "
Et
2
O
Ln D Y,
350
La
349b
3HOR
f
![Ln
OR
f
3
] C 3
Me
3
Si
2
NH "
benzene
Ln D Y,
349a
La, Pr, Eu,
349a
R
f
D CMe
CF
3
2
Ln D Y,
349a
R
f
D CMe
2
CF
3
3HOCBu
t
3
![Tm
OCBu
t
3
3
NH
2
SiMe
2
]
2
CH
2
Ln D Tm
353
Scheme 2.2
Reaction of LnfN
SiMe
3
2
g
3
with sterically demanding monodentate alcohols.
