Chemistry Reference
In-Depth Information
NBu
4
3
[
MeO
TiW
5
O
5
6
-O
-O
12
]
6, 6
t,
6
,
TiO
6
, 2.211 (11)
TiO(
), 1.931 - 1.967 (11)
-
81
av. 1.947
WO(
6
), 2.333 av.
WO(
), 1.914 av.
WO,1.719av.(t)
[Zr
13
4
-O
8
-OMe
24
-OMe
12
]
7, 8
4
2.19, 2.23 (1)
-
123
[Zr
3
3
-O
3
-Cl
-OCH
2
Bu
t
3
OCH
2
Bu
t
6
]
6
3
2.082, 2.089, 2.090 (3)
104. 4 av.
98
[Zr
3
3
-O
3
-OBu
t
-OH
-OBu
t
2
OBu
t
6
]
6
3
2.094, 2.108 (4)
100.1, 101.9
98
[Zr
3
Pb
4
-O
3
-OPr
i
2
-OPr
i
4
-OAc
2
OPr
i
4
]
6 (Zr)
4
ZrO, 2.15, 2.22, 2.23 (1)
-
121
5 (Pb)
PbO, 2.310 (9)
[Zr
4
Pb
2
4
-O
2
-OEt
8
-OAc
2
OEt
4
OAc
2
]
6, 7 (Zr)
4(Pb)
4
ZrO, 2.17
PbO, 2.32
-
126
[ZrPb
3
4
-O
3
-OBu
t
-OBu
t
5
OBu
t
2
]
6 (Zr)
4
ZrO, 2.23 (4)
ZrOPb, 100.9, 101.0, 127.8
22
5, 3 (Pb)
PbO, 2.15, 2.26, 2.26 (3)
Pb
2
O, 100.8, 111.2, 111.6
[Zr
3
Fe
4
-O
-Pr
n
6
OPr
n
4
acac
3
]
7 (Zr)
4
ZrO, 2.106, 2.111, 2.123 (8)
Zr
2
O, 114.3, 114.5, 114.7
127
5 (Fe)
FeO, 2.124 (9)
ZrOFe, 104.0, 104.6, 104.8
[Zr
2
Co
4
6
-O
-OPr
n
8
OPr
n
2
acac
4
]
6, 6
6
ZrO, 2.207 (1)
CoO, 2.363, 2.377 (1)
90, 180
128
[Zr
4
Cu
4
4
-O
-OPr
i
10
OPr
i
8
]
2 (Cu)
6(Zr)
4
CuO, 1.821 - 1.843 (9)
av. 1.830
Cu
2
O, 94.2, 94.4, 102.3,
119.4, 122.8, 125.0
129
[Zr
4
Cu
4
4
-O
3
-OPr
i
10
OPr
i
8
]
4 (Cu)
4
ZrO, 2.214, 2.231 (11)
Cu
2
O, 90, 180
129
6 (Zr)
CuO, 1.9655, 1.9679 (25)
Cu
2
O, 94.9
ZrOCu, 98.1, 98.6, 140.3,
144.3
Zr
2
O, 92.3
oct D octahedral, t D terminal, tet D tetrahedral.
