Chemistry Reference
In-Depth Information
Ti, Zr,
Hetero-
M-O Bond lengths ( A)
Bond angles (
Ž
)
MOC
Compound
Hf
metal
Terminal
Bridging
Reference
[Ti
,
2
-OCMe
2
CH
2
PPh
2
3
Rh]
4
1
4
1
TiO, 1.827 - 1.833 (4)
-
TiO, 137.9 - 144.1
508
av. 1.830
av. 141.9
[ClCufTi
2
OPr
i
9
g]
6
5
TiO, 1.772 - 1.790 (2)
av. 1.780
CuO, 2.149, 2.157 (2) (
3
)
2.007, 2.008 (2) (
)
TiO, 2.088 - 2.155 (2) (
3
)
av. 2.124
1.981 - 2.087 (2) (
)
av. 2.029
-
493
[ICdfTi
2
OPr
i
9
g]
6
5
TiO, 1.774 (4)
CdO, 2.281 (5) (
3
)
2.337, 2.343 (6) (
)
TiO, 2.107 - 2.167 (5) (
3
)
av. 2.149
1.925 - 2.047 (7) (
)
av. 2.004
-
495
[SnfTi
2
OPr
i
9
g]
C
SnCl
3
6
5
1
TiO, 1.755 (4)
SnO, 2.214, 2.164 (4) (
3
)
2.321, 2.422 (4) (
)
TiO, 2.014, 2.027 (4) (
)
-
509
[fTi
OPr
i
4
gfOPb
4
NBu
t
3
g]
5
3
TiO 1.76 (5) (ax)
TiO 1.83 (3) (eq)
TiO, 2.09 (3) (
4
)
PbO, 2.23 (3) (
4
)
-
510
[Zr
2
Co
2
3
-OPr
n
2
-
OPr
n
4
OPr
n
4
acac
2
]
6
5
ZrO, 1.913, 1.928 (7)
Co(acac),
1.924, 2.014 (6)
ZrO, 2.225 - 2.229 (5) (
3
)
2.138, 2.144 (5) (
)
CoO, 2.454 (5) (
3
)
1.930, 1.935 (5) (
)
ZrO, 168.3, 171.6 (t)
ZrO, 127.6 (
,b)
CoO, 120.3
511
[ClCufZr
2
OPr
i
g
9
]
6
5
ZrO, 1.914 - 1.936 (6)
av. 1.926
ZrO, 2.221 - 2.257 (6) (
3
)
av. 2.240
2.092 - 2.208 (6) (
)
av. 2.145
CuO, 2.186, 2.207 (6) (
3
)
1.998, 1.999 (6) (
)
ZrO, 172.9 - 174.4 (t)
ZrO, 123.6 - 133.3 (
3
,b)
128.5 - 138.4 (
,b)
CuO, 114.0 - 116.7 (
3
,b)
124.4, 132.6 (
,b)
512
