Chemistry Reference
In-Depth Information
M-O Bond lengths ( A)
Bond angles (
Ž
)
Metal
MOC
Compound
coordination
Terminal
Bridging
Reference
[Ni
4
-OMe
4
MeOH
4
OC
6
H
4
CHO
4
]
6
2.099 (9) (MeOH)
2.019, 2.043,
2.054 (8)
117.2, 120.7,
120.8 (b)
400
[Ni
2
fOC
CF
3
2
CH
2
CMeDN
CH
2
6
NDCMeCH
2
C
CF
3
2
Og
2
]
4
1.841, 1.843 (2)
-
-
401
[NifO
2
C
2
CF
3
4
g
2
]
2
4
1.852 (3)
-
111.8
402
[Ni
4
-OMe
4
MeOH
4
OC
6
H
2
Cl
3
4
]
6
2.06 - 2.09 (MeOH)
av. 2.08
2.02 - 2.08
av. 2.04
118 - 123
403
[NifOC
CF
3
2
CH
2
C(Me)
D
NC
2
H
4
C
6
H
4
Ng
2
]
6
2.086 (4)
-
126.6
404
[NifOC
CF
3
2
CH
2
PPh
2
g
2
]
4
1.837 - 1.844 (7)
av. 1.839
-
121.1 - 123.9
405
[NifO
2
C
CF
3
2
gL]
L D
cyclo
-N
D
C(Me)CH
2
C(Me)
2
NH
C
3
H
6
NH
C
3
H
6
5
2.037, 2.039 (4)
-
91.1, 91.4
406
[NifOC
CF
3
2
CH
2
C(O)
D
CHC
CF
3
2
OHg
Me
2
NC
2
H
4
NMe
2
]
4
1.825, 1.897
-
119.4, 123.1
407
[Ni
4
-OMe
4
MeOH
4
fPhCO(CH)COPhg
4
]
6
-
2.015 - 2.072 (9)
av. 2.045
-
408
[PdfOC
CF
3
2
CH
2
PPh
2
gCl
PMe
2
Ph
]
4
2.046 (2)
-
122.7
409
[PdfOC
CF
3
2
C
6
H
4
SMegCl
PMePh
2
]
4
2.053 (3)
-
125.0
410
[Pt
OMe
2
Ph
2
PC
2
H
4
PPh
2
]
4
2.037, 2.041 (7)
-
117.0, 121.0
411
[Pt(OMe)Me
Ph
2
PC
2
H
4
PPh
2
]
4
1.990 (10)
-
119
411
[PtfOC
CF
3
2
CH
2
SMeg
PPh
3
2
]
BF
4
4
2.041 (5)
-
121.2
412
[PtfOC
CF
3
2
CH
2
SMeg
PMePh
2
]
BF
4
4
2.058 (6)
-
117.3
412
[PtfOC
CF
3
2
CH
2
PPh
2
g
2
]
4
2.030 - 2.034 (6)
-
-
413
[PtfO
2
C
CF
3
2
g
PPh
3
2
]
4
2.040, 2.056 (5)
-
91.8, 92.2
414
[Pt
OCH
2
CH
2
PPh
2
2
]
4
2.039 (5)
-
114.8
416
[PtfOCH
CF
3
2
gMe
PMe
3
2
]
4
2.07 (1)
-
125.3
417
[PtfOCH
CF
3
2
gfHOCH
CF
3
2
gMe
PMe
3
2
]
4
2.07 (3)
-
123
418
[Pt(D-mannitolate)(DPPP)]
4
2.033, 2.042 (9)
-
-
419
b D bridging.
