Chemistry Reference
In-Depth Information
Compound
coordination
Terminal
Bridging
MOC
Reference
[Mo
2
-OCH
2
Bu
t
f
-C
4
Me
3
CH
2
NEt
2
NHg
OCH
2
Bu
t
5
]
6
1
1.890 - 1.944 (5)
av. 1.928
2.127, 2.135 (5)
128.8 - 143.9 (t)
av. 135.9
125.2, 125.9 (b)
249
[Mo
2
-OPr
i
2
OPr
i
4
O
2
C
6
Cl
4
2
]
6
1.817, 1.844 (5)
Pr
i
O
2.014, 2.016 (5)
(Diol)
2.020, 2.026 (5)
140.1, 165.1 (t)
134.2, 139.5 (b)
250
[Mo
2
-OPr
i
2
OPr
i
2
O
2
C
14
H
8
3
6
1.840, 1.845 (4)
Pr
i
O
1.941 - 2.030 (4)
(Diol)
av. 1.984
1.974, 1.979 (4)
(Mo[1])
2.045, 2.061 (4)
(Mo[2])
151.7, 154.3 (t)
131.9 - 142.0 (b)
av. 136.9
250
[Mo
2
-OPr
i
2
OPr
i
4
Pr
i
NC
2
H
2
NPr
i
]
5
1.887, 1.894,
1.919 (3)
1.981, 2.097 (4)
(Mo[1])
1.959, 2.147 (4)
(Mo[2])
-
251
[Mo
2
-NMe
2
2
NMe
2
2
OC
6
H
10
-4-Me
4
]
5
1.990, 1.966 (2)
-
-
252
4
1
[Mo
2
fOC
CF
3
3
g
4
NMe
2
2
]
1.909, 1.923 (10)
-
147.2, 164.2
253
[Mo
2
fOCMe
CF
3
2
g
6
]
4
1
1.88 (1)
-
149
255
Mo
2
-NAr
2
OBu
t
4
]
Ar D 2
,
6-diisopropylphenyl
4
1.887, 1.892 (3)
-
-
256
[Mo
2
OBu
t
4
NHPh
2
NH
2
Ph
2
]
5
1
1.926 - 1.979 (4)
av. 1.954
-
132.8 - 144.3
av. 140.5
257
4
1
[Mo
2
fO
12
Si
7
C
6
H
11
-
c
7
g
2
]
av. 1.90 (1)
-
-
258
[Mo
2
-OCH
2
Bu
t
OCH
2
Bu
t
6
]
5
1
1.921 - 1.975 (6)
av. 1.951
2.143 - 2.159 (6)
av. 2.150
-
259
[
Bu
t
CH
2
O
4
Mo
-OCH
2
Bu
t
-
S
Mo
OCH
2
Bu
t
CPh
2
PMe
3
]
5 and 6
1.861 - 1.945 (6)
av. 1.913
2.116, 2.119 (6)
-
260
[Mo
4
-F
4
OBu
t
8
]
5
1
1.850 - 1.992(6)
av. 1.925
-
114.3 - 165.7
av. 139.5
261
