Chemistry Reference
In-Depth Information
Metal
Bond angles (
Ž
)
MOC
Compound
coordination
Terminal
Bridging
Reference
[Ti
2
-OPr
n
2
OPr
n
4
tmhd
2
]
137.3, 145.8 (t, Pr
n
O)
112, 137 (b, Pr
n
O)
134.2, 135.7 (tmhd)
6
1.783, 1.792 (7)
Pr
n
O
1.998, 2.055 (2)
(tmhd)
1.940, 2.069 (6)
178
[Ti
2
-OPr
i
2
OPr
i
4
thmd
2
]
129.8, 151.0 (t, Pr
i
O)
123.2, 129.8 (b, Pr
i
O)
134.5, 135.3 (tmhd)
6
1.802, 1.816 (1)
Pr
i
O
2.043, 2.075 (1)
(tmhd)
1.968, 2.094 (1)
178
[Ti
4
f
3
-OCH
2
CMe
CH
2
O-
2
g
2
OPr
i
10
]
2.04
,
L
1
2.20
3
,
L
1
6
1.787 - 1.839 (1)
Pr
i
O
120 (
,L,av.)
114.3, 115.9, 121.8 (
3
,L)
179
[Ti
4
f
3
-OCH
2
CEt
CH
2
O-
2
g
2
OPr
i
10
]
2.04
,
L
1
2.20
3
,
L
1
6
1.787 - 1.839 (1)
Pr
i
O
119 (
,L,av.)
114.2, 116.2, 121.2 (
3
,L)
179
[Ti
5
4
-OC
2
H
4
O
3
-OC
2
H
4
O
3
-
OC
2
H
4
O
-OPr
i
OPr
i
9
]
7, 6, 5
1.72 - 1.81
Pr
i
O
av. 1.77 (1)
1.85 (1)
(OC
2
H
4
,av.)
1.93, 2.11 (1)
Pr
i
O
2.00, 2.26 (1)
OC
2
H
4
152.8 (t, Pr
i
O
180
Na
2
[Ti
OC
2
H
4
O
3
]
HOC
2
H
4
OH
4
6
1.915 - 1.969 (4)
av. 1.953
-
112.1 - 117.3
av. 115.0
181
K
2
[Ti
OC
2
H
4
O
3
]
HOC
2
H
4
OH
2
.
5
6
1.899 - 1.986 (2)
av. 1.943
-
110.9 - 118.3
av. 115.0
181
[Ba
HOC
2
H
4
OH
4
H
2
O
9
]
2C
[Ti
OC
2
H
4
O
3
]
2
6
av. 1.93 (2)
-
-
182
[Ti
2
-OEt
2
OEt
4
O
2
CCH
2
NH
2
2
]
6
1.765, 1.813 (6)
(EtO)
1.981 (6) (glycinate)
1.955, 2.087 (5)
-
183
[Ti
2
-OMe
2
fO
12
Si
7
C
6
H
11
7
g
MeOH
]
6
1.837 (7) (silsesq)
2.210 (7) (MeOH)
2.004, 2.022 (7)
(
,MeO)
-
184
[TifO
12
Si
7
C
6
H
11
7
g
OSiMe
3
]
4
1.84 (2)
Me
3
SiO
-
180
Me
3
SiO
185
[
C
6
H
5
CH
2
4
Ti
2
-OEt
2
OEt
2
]
5
1.837 (8)
1.865, 2.104 (7)
176.0 (t)
122.1, 130.6 (b)
186
