Chemistry Reference
In-Depth Information
Compound
coordination
Terminal
Bridging
MOC
Reference
[Mg
4
3
-OMe
4
OMe
4
MeOH
8
]
6
2.04 - 2.13 (1)
(av. 2.09)
2.05 - 2.12 (1)
(av. 2.09)
-
41
[Mg
4
3
-OMe
4
OMe
2
MeOH
10
]
2C
6
2.01 - 2.15 (1)
(av. 2.09)
2.05 - 2.14 (1)
(av. 2.09)
-
41
[Ca
9
3
-OR
8
-OR
8
OR
8
HOR
2
]
R D C
2
H
4
OMe
6 and 7
2.313 (9)
av.
, 2.291 (8)
av.
3
, 2.390 (8)
-
43
[Ca
-OR
OR
thf
]
2
R D OCPh
2
CH
2
C
6
H
4
Cl
4
2.105 (2)
2.268 (2)
167.4 (t)
132.2, 123.9 (b)
44
[Ca
2
-OSiPh
3
3
OSiPh
3
NH
3
4
]
5 and 6
2.179 (5)
av. Ca (6) 2.374 (5)
av. Ca (5) 2.265 (5)
162.9 (t)
141.5 (b, av.)
132.5 (b, av.)
45
[Ca
2
,
3
-L
,
2
-L
2
2
-L
]
L D Bu
t
Pr
i
OCH
2
2
CO
6
alkoxo, 2.181 (4)
ether, 2.531 (8)
2.269, 2.362 (8)
-
444
[Sr
OSiPh
3
2
15-crown-5
thf
]
8
2.363, 2.322 (6)
-
168.2, 167.3
46
[Sr
3
-OSiPh
3
3
-OSiPh
3
tmhd
3
]
tmhd D Bu
t
CO
CH
COBu
t
5and6
-
(
) 2.436, 2.440 (3)
(
3
) av. 2.524 and
2.549 (3)
(
) 144.3, 121.2
(
3
) 118.9 - 133.8
47
[Sr
3
fO
SiPh
2
O
2
g
3
tetraglyme
2
]
6 and 7
-
2.414 - 2.608 (6)
av. 2.493
-
47
[Ba
3
3
-OSiPh
3
2
-OSiPh
3
3
OSiPh
3
thf
]
4 and 5
2.472 (4)
av.
3
,2.69(9)
av.
,2.64(4)
-
48
[BafOC
2
H
4
N
C
2
H
4
OH
2
g
2
]
8
2.73 - 2.78 (1)
(av. 2.75)
-
124.3 - 126.6
(av. 125.2)
49
[Ba
2
-OCPh
3
3
OCPh
3
thf
3
]
5
2.409 (4)
2.544 - 2.650 and 2.835
163.5 (t)
50
[Ba
2
-OSiBu
t
3
3
OSiBu
t
3
thf
]
4
2.413 (16)
2.461 - 2.832 (21)
av. 2.60
174.7 (t)
129.2 - 135.1 (b)
50
[Ba
5
5
-OH
3
-hfip
4
-hfip
4
hfip
thf
4
H
2
O
]
hfip D OCH
CF
3
2
6and7
2.64(2)
av.
D 2
.
63 (3)
av.
3
D 2
.
76 (3)
126.8 (t)
51
[Ba
OSiPh
3
2
15-crown-5
thf
]
8
2.466, 2.482 (4)
-
166.9, 160.5
46
[Ba
4
3
-OBu
t
4
OBu
t
4
Bu
t
OH
8
]
6
2.673 (8)
3
, 2.675 - 2.728 (6)
av. 2.702
148.6 - 170.2 (t)
115.3 - 118.1 (b)
52
b D bridging, t D terminal.
