Chemistry Reference
In-Depth Information
Table 2.1
(
Continued
)
Method of
Characterization
Compound
1
preparation
2
techniques
3
Reference
W
4
OPr
i
12
/
W
2
OPr
i
6
1
HNMR;MS;
X-ray
Crystallization of
W
2
OPr
i
6
from
dimethoxyethane
1
H,
13
C,
95
Mo
M
4
OCH
2
R
12
M D Mo, W
R D c-C
4
H
7
,c-C
5
H
9
,
c-C
6
H
11
,Pr
i
alcoholysis of
M
2
OBu
t
6
IR;
k
NMR;
X-ray (M D Mo;
R D c-C
4
H
7
)
1
H NMR; X-ray
W
4
OEt
16
I
366
Group 7
[Mn
OR
2
]
n
R D primary, secondary, and
tertiary alcohols
I
Reflectance spectra;
eff
l
[Mn
OCHBu
t
2
2
]
2
I
IR; UV-Vis; ESR;
MW
226
I
X-ray
351
Mn[OCBu
t
CH
2
OPr
i
2
]
2
I
IR; MS
340
Re
3
OPr
i
9
E-2
1
H NMR; X-ray
173, 174
Group 8
[FefOCBu
t
CH
2
OEt
2
g
2
]
2
I
IR; MS
340
Group 9
[Co
OCHBu
t
2
2
]
2
I
IR; UV-Vis; MW
226
IR;
1
HNMR;
UV-Vis; X-ray
[Co
OCPh
3
2
]
2
.
n
-C
6
H
14
I
351a
Co
OCPh
3
2
thf
2
I(THFusedas
solvent)
IR;
1
HNMR;
UV-Vis; X-ray
351a
Co[OCBu
t
CH
2
OPr
i
2
]
2
I
IR; MS
340
[Co[OC
CF
3
CH
2
OPr
i
2
]
2
]
2
I
IR; MS
340
Group 10
[Ni
OR
2
]
n
R D Me, Et, Pr
n
,Pr
i
,Bu
t
,Am
t
,
t-C
6
H
13
E-3
6, 219
Ni[OCBu
t
CH
2
OPr
i
2
]
2
E-2
IR; MS
340
1
H,
31
P NMR; X-ray
dppe
Pt
OMe
2
E-2
177, 177a
Pt
OCH
2
CH
2
PPh
2
2
E-2
IR;
1
H,
31
PNMR;
MS; X-ray
178
IR;
1
H,
31
PNMR;
X-ray
Pt
OCMe
2
CH
2
PPh
2
2
E-2
178a
Pt
OCMe
2
CH
2
PPh
2
.
3
.
5H
2
O
1
H,
31
P NMR; X-ray
I
178b
Group 11
[Cu
OCHBu
t
2
]
4
E-3
MW
226
[CuOBu
t
]
4
E-3
m
E-3
IR;
1
HNMR;ESR
n, o
1
H NMR; X-ray
CufOCH
CF
3
2
g
PPh
3
3
J-2
IR;
p
1
HNMR
Cu
OCHPh
2
PPh
3
3
J-2
IR;
p
[CuOCEt
3
]
4
E-2
1
H,
13
CNMR;MW 47
(
continued overleaf
)
