Chemistry Reference
In-Depth Information
10.1
(
1 1.7 )
not
found
TS-2
P
t
Bu
3
7.7
(5.9)
6.4
(3 .1)
TS-1
7.47a
2.7
(
12.6)
TS-3
7.49a
0.0
(0 .0)
-1.9
(- 1.4
)
PdL
P
t
Bu
3
7.46a
-7.2
(- 6.2
)
PdL
2
7.51a
7.48a
-17.2
(-18.1)
-18.7
(-20.7
)
7.50a
PdL
2
L
Pd
X
L
L
Pd
X
Pd
X
O
O
O
TS-1
TS-2
TS-3
L
L
L
PdL
2
Pd
X
X
Pd
X
Pd
PdL
2
Pd
Pd
X
X
L
L
O
O
O
O
O
X
X
7.47
7.48
7.49
7.50
7.51
O
O
X = I,
7.46a
X = Br,
7.46b
X = Cl,
7.46c
7.52
Scheme 7.28 Proposed catalytic cycle for Pd-catalyzed carbohalogenation.
Adapted from Ref. 100 with permission.
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